Unexpected energy applications of ionic liquids
Ionic liquids and their various analogues are without doubt the scientific sensation of the last
few decades, paving the way to a more sustainable society. Their versatile suite of …
few decades, paving the way to a more sustainable society. Their versatile suite of …
Lewis acidic ionic liquids
Until very recently, the term Lewis acidic ionic liquids (ILs) was nearly synonymous with
halometallate ILs, with a strong focus on chloroaluminate (III) systems. The first part of this …
halometallate ILs, with a strong focus on chloroaluminate (III) systems. The first part of this …
High Coulombic efficiency aluminum-ion battery using an AlCl3-urea ionic liquid analog electrolyte
In recent years, impressive advances in harvesting renewable energy have led to a pressing
demand for the complimentary energy storage technology. Here, a high Coulombic …
demand for the complimentary energy storage technology. Here, a high Coulombic …
Hydrophobic deep eutectic solvents incorporating trioctylphosphine oxide: Advanced liquid extractants
M Gilmore, EN McCourt, F Connolly… - ACS Sustainable …, 2018 - ACS Publications
A low viscosity, hydrophobic eutectic solvent based on trioctylphosphine oxide (TOPO) has
been developed and characterized, and its use as an extractant demonstrated for liquid …
been developed and characterized, and its use as an extractant demonstrated for liquid …
Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries
A polymer gel electrolyte using AlCl3 complexed acrylamide as a functional monomer and
acidic ionic liquid based on a mixture of 1-ethyl-3-methylimidazolium chloride (EMImCl) and …
acidic ionic liquid based on a mixture of 1-ethyl-3-methylimidazolium chloride (EMImCl) and …
[HTML][HTML] Ionic liquids as modifier for the oligomerization of α-olefins to reactive poly (α-olefins) via traditional AlCl3 catalyst
In the polymerization there are series of systems that are traditionally used because their
procedures are well established, and it is not considered necessary to leave the comfort …
procedures are well established, and it is not considered necessary to leave the comfort …
[HTML][HTML] An efficient initiator system containing AlCl3 and supported ionic-liquid for the synthesis of conventional grade polyisobutylene in mild conditions
Ionic liquid based systems are used to facilitate the cationic polymerization of isobutylene to
conventional grade polyisobutylene (PIB) using AlCl 3 as an initiator. Specifically, the …
conventional grade polyisobutylene (PIB) using AlCl 3 as an initiator. Specifically, the …
Coordinative chain transfer polymerization of 1-decene in the presence of a Ti-based diamine bis (phenolate) catalyst: A sustainable approach to produce low …
A Ti-based diamine bis (phenolate) catalyst,[Ti {2, 2′-(OC6H2-4, 6-tBu2) 2NHMePhMeNH}
Cl2], was synthesized and fully characterized by elemental analysis and NMR spectroscopy …
Cl2], was synthesized and fully characterized by elemental analysis and NMR spectroscopy …
Group IIIA halometallate ionic liquids: Speciation and applications in catalysis
Group IIIA halometallate ionic liquids (ILs) present fascinating properties for the field of
catalysis, particularly through the ability to tune their Lewis acidity solely by changing the …
catalysis, particularly through the ability to tune their Lewis acidity solely by changing the …
Structural and Spectroscopic Characterizations of Amide–AlCl3-Based Ionic Liquid Analogues
P Hu, R Zhang, X Meng, H Liu, C Xu, Z Liu - Inorganic chemistry, 2016 - ACS Publications
Several amide–AlCl3-based ionic liquid (IL) analogues were synthesized through a one-
step method using three different structure amides as donor molecules. The effects of the …
step method using three different structure amides as donor molecules. The effects of the …