Carbon nitride based materials: more than just a support for single-atom catalysis

GFSR Rocha, MAR da Silva, A Rogolino… - Chemical Society …, 2023 - pubs.rsc.org
Recently, the missing link between homogeneous and heterogeneous catalysis has been
found and it was named single-atom catalysis (SAC). However, the SAC field still faces …

Single atoms meet metal–organic frameworks: collaborative efforts for efficient photocatalysis

H Liu, M Cheng, Y Liu, J Wang, G Zhang, L Li… - Energy & …, 2022 - pubs.rsc.org
Photocatalysts with metal single atoms (SAs) as active sites have attracted widespread
interest owing to their maximum atomic utilization efficiency, well-defined active centers and …

Reversed Electron Transfer in Dual Single Atom Catalyst for Boosted Photoreduction of CO2

Y Zhang, B Johannessen, P Zhang, J Gong… - Advanced …, 2023 - Wiley Online Library
Photogenerated charge localization on material surfaces significantly affects photocatalytic
performance, especially for multi‐electron CO2 reduction. Dual single atom (DSA) catalysts …

Dual optimization approach to Mo single atom dispersed g-C3N4 photocatalyst: morphology and defect evolution

C Zhang, D Qin, Y Zhou, F Qin, H Wang… - Applied Catalysis B …, 2022 - Elsevier
Reasonable regulation of the interaction between metal center and the ligand to achieve a
high-density atomic loading without agglomeration has been the formidable challenge to the …

Emerging Cocatalysts on g‐C3N4 for Photocatalytic Hydrogen Evolution

Q Zhu, Z Xu, B Qiu, M **ng, J Zhang - Small, 2021 - Wiley Online Library
Over the past few decades, graphitic carbon nitride (g‐C3N4) has arisen much attention as a
promising candidate for photocatalytic hydrogen evolution reaction (HER) owing to its low …

Pt Single Atoms Supported on N‐Doped Mesoporous Hollow Carbon Spheres with Enhanced Electrocatalytic H2‐Evolution Activity

P Kuang, Y Wang, B Zhu, F **a, CW Tung… - Advanced …, 2021 - Wiley Online Library
The electronic metal–support interaction (EMSI) plays a crucial role in catalysis as it can
induce electron transfer between metal and support, modulate the electronic state of the …

Semiconducting metal–organic frameworks decorated with spatially separated dual cocatalysts for efficient uranium (VI) photoreduction

K Yu, L Tang, X Cao, Z Guo, Y Zhang… - Advanced Functional …, 2022 - Wiley Online Library
Reduction of soluble hexavalent uranium (U (VI)) to sparingly soluble tetravalent uranium (U
(IV)) with semiconductor photocatalysts is recognized as a novel, green, and simple U …

Isolating single and few atoms for enhanced catalysis

Y Chen, J Lin, B Jia, X Wang, S Jiang… - Advanced …, 2022 - Wiley Online Library
Atomically dispersed metal catalysts have triggered great interest in the field of catalysis
owing to their unique features. Isolated single or few metal atoms can be anchored on …

Electronic metal–support interaction of single‐atom catalysts and applications in electrocatalysis

J Yang, W Li, D Wang, Y Li - Advanced Materials, 2020 - Wiley Online Library
The electronic metal–support interaction (EMSI), which acts as a bridge between theoretical
electronic study and the design of heterogenous catalysts, has attracted much attention …

Oxo dicopper anchored on carbon nitride for selective oxidation of methane

P **e, J Ding, Z Yao, T Pu, P Zhang, Z Huang… - Nature …, 2022 - nature.com
Selective conversion of methane (CH4) into value-added chemicals represents a grand
challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric …