MOFs with bridging or terminal hydroxo ligands: Applications in adsorption, catalysis, and functionalization

I Ahmed, MMH Mondol, MJ Jung, GH Lee… - Coordination Chemistry …, 2023‏ - Elsevier
Metal-organic frameworks (MOFs) are popular porous materials prepared from metallic
species and organic linkers via the formation of coordination bonds. The applications and …

Tuning redox activity in metal–organic frameworks: From structure to application

SAA Razavi, W Chen, HC Zhou, A Morsali - Coordination Chemistry …, 2024‏ - Elsevier
Among the various characteristics of metal–organic frameworks (MOFs), redox activity, the
ability to store or release electrons is a vital property for functional MOFs in applications like …

Photocatalytic CO2 Reduction with Dissolved Carbonates and Near-Zero CO2(aq) by Employing Long-Range Proton Transport

R Yanagi, T Zhao, M Cheng, B Liu, H Su… - Journal of the …, 2023‏ - ACS Publications
Photocatalytic CO2 reduction (CO2R) in∼ 0 mM CO2 (aq) concentration is challenging but
is relevant for capturing CO2 and achieving a circular carbon economy. Despite recent …

High Gravimetric and Volumetric Ammonia Capacities in Robust Metal–Organic Frameworks Prepared via Double Postsynthetic Modification

DW Kim, DW Kang, M Kang, DS Choi… - Journal of the …, 2022‏ - ACS Publications
Ammonia is a promising energy vector that can store the high energy density of hydrogen.
For this reason, numerous adsorbents have been investigated as ammonia storage …

Metal–organic framework composites from a mechanochemical process

W Wang, M Chai, MYB Zulkifli, K Xu, Y Chen… - … Systems Design & …, 2023‏ - pubs.rsc.org
Metal–organic frameworks (MOFs) consist of metal ions or clusters coordinated with organic
ligands such as imidazolate or carboxylate ligands. Owing to the high porosity and surface …

A universal method for constructing high efficiency organic solar cells with stacked structures

Y Wei, J Yu, L Qin, H Chen, X Wu, Z Wei… - Energy & …, 2021‏ - pubs.rsc.org
The construction of organic solar cells with stacked structures by the sequential deposition
(SD) of donor and acceptor films has great potential in industrial production, as it …

Excited-State Intramolecular Proton-and Inter-Polymer Charge-Transfer of Semiconducting Redox Polymers for Fe (III), Cd (II), and Hg (II) Sensing

M Deb, S Roy, M Mitra, JS Deb Roy… - ACS Applied Polymer …, 2024‏ - ACS Publications
Herein, IPCT-ESIPT exhibiting nonconventional fluorescent semiconducting polymers (FSP
s) are synthesized using poly (vinyl alcohol)(PVA), 2-acrylamido-2-methylpropanesulfonic …

Selective adsorption of oxygen from humid air in a metal–organic framework with trigonal pyramidal copper (I) sites

KM Carsch, AJ Huang, MN Dods… - Journal of the …, 2024‏ - ACS Publications
High or enriched-purity O2 is used in numerous industries and is predominantly produced
from the cryogenic distillation of air, an extremely capital-and energy-intensive process …

Metal–organic frameworks as O 2-selective adsorbents for air separations

DE Jaramillo, A Jaffe, BER Snyder, A Smith, E Taw… - Chemical …, 2022‏ - pubs.rsc.org
Oxygen is a critical gas in numerous industries and is produced globally on a gigatonne
scale, primarily through energy-intensive cryogenic distillation of air. The realization of large …

CO2 Adsorption in a Robust Iron(III) Pyrazolate‐Based MOF: Molecular‐Level Details and Frameworks Dynamics From Powder X‐ray Diffraction Adsorption …

R Vismara, S Terruzzi, A Maspero, T Grell… - Advanced …, 2024‏ - Wiley Online Library
Understanding adsorption processes at the molecular level, with multi‐technique
approaches, is nowadays at the frontier of porous materials research. In this work it is shown …