Molecular views on mechanisms of Brønsted acid-catalyzed reactions in zeolites
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …
applications of these materials in heterogeneous catalysis, mainly in the fields of …
Activation and conversion of alkanes in the confined space of zeolite-type materials
Microporous zeolite-type materials, with crystalline porous structures formed by well-defined
channels and cages of molecular dimensions, have been widely employed as …
channels and cages of molecular dimensions, have been widely employed as …
Aromatics production via methanol-mediated transformation routes
The methanol-to-aromatics (MTA) process is regarded as a promising route to produce
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …
Advances in theory and their application within the field of zeolite chemistry
Zeolites are versatile and fascinating materials which are vital for a wide range of industries,
due to their unique structural and chemical properties, which are the basis of applications in …
due to their unique structural and chemical properties, which are the basis of applications in …
Lewis–Brønsted acid pairs in Ga/H-ZSM-5 to catalyze dehydrogenation of light alkanes
MW Schreiber, CP Plaisance… - Journal of the …, 2018 - ACS Publications
The active sites for propane dehydrogenation in Ga/H-ZSM-5 with moderate concentrations
of tetrahedral aluminum in the lattice were identified to be Lewis–Brønsted acid pairs. With …
of tetrahedral aluminum in the lattice were identified to be Lewis–Brønsted acid pairs. With …
Engineering zeolites for catalytic cracking to light olefins
Propene is a key building block for the petrochemical industry whose demand is increasing
strongly in recent years, even faster than that of ethene. The availability of propene is limited …
strongly in recent years, even faster than that of ethene. The availability of propene is limited …
Molecular simulations of zeolites: adsorption, diffusion, and shape selectivity
B Smit, TLM Maesen - Chemical reviews, 2008 - ACS Publications
Zeolites are intriguing materials. The basic building blocks are corner sharing TO4 units,
where the T-atoms usually refer to Si, Al, or in some cases also P. These tetrahedrals can …
where the T-atoms usually refer to Si, Al, or in some cases also P. These tetrahedrals can …
Size-dependent reaction mechanism and kinetics for propane dehydrogenation over Pt catalysts
J Zhu, ML Yang, Y Yu, YA Zhu, ZJ Sui, XG Zhou… - Acs …, 2015 - ACS Publications
Platinum cluster size has a significant influence on the activity, selectivity, and stability as
well as the reaction mechanism during propane dehydrogenation (PDH). Well-controlled …
well as the reaction mechanism during propane dehydrogenation (PDH). Well-controlled …
The catalytic diversity of zeolites: confinement and solvation effects within voids of molecular dimensions
The ability of molecular sieves to control the access and egress of certain reactants and
products and to preferentially contain certain transition states while excluding others based …
products and to preferentially contain certain transition states while excluding others based …