Structural transformations in boron clusters induced by metal do**

J Barroso, S Pan, G Merino - Chemical Society Reviews, 2022 - pubs.rsc.org
In the last decades, experimental techniques in conjunction with theoretical analyses have
revealed the surprising structural diversity of boron clusters. Although the 2D to 3D transition …

Probing the structures and bonding of size-selected boron and doped-boron clusters

T Jian, X Chen, SD Li, AI Boldyrev, J Li… - Chemical Society …, 2019 - pubs.rsc.org
Because of their interesting structures and bonding and potentials as motifs for new
nanomaterials, size-selected boron clusters have received tremendous interest in recent …

Describing chemical reactivity with frontier molecular orbitalets

J Yu, NQ Su, W Yang - JACS Au, 2022 - ACS Publications
Locality in physical space is critical in understanding chemical reactivity in the analysis of
various phenomena and processes in chemistry, biology, and materials science, as …

Photoelectron spectroscopy of size-selected boron clusters: from planar structures to borophenes and borospherenes

LS Wang - International Reviews in Physical Chemistry, 2016 - Taylor & Francis
Photoelectron spectroscopy (PES) in combination with computational chemistry has been
used systematically over the past decade to elucidate the structures and chemical bonding …

Be2C Monolayer with Quasi‐Planar Hexacoordinate Carbons: A Global Minimum Structure

Y Li, Y Liao, Z Chen - Angewandte Chemie International …, 2014 - Wiley Online Library
The design of new materials is an important subject in order to attain new properties and
applications, and it is of particular interest when some peculiar topological properties such …

Four decades of the chemistry of planar hypercoordinate compounds

LM Yang, E Ganz, Z Chen, ZX Wang… - Angewandte Chemie …, 2015 - Wiley Online Library
The idea of planar tetracoordinate carbon (ptC) was considered implausible for a hundred
years after 1874. Examples of ptC were then predicted computationally and realized …

Unravelling chemical interactions with principal interacting orbital analysis

JX Zhang, FK Sheong, Z Lin - Chemistry–A European Journal, 2018 - Wiley Online Library
Decomposing chemical interactions into bonds and other higher order interactions is a
common practice to analyse chemical structures, and gave birth to many chemical concepts …

All-boron analogues of aromatic hydrocarbons: B17− and B18−

AP Sergeeva, BB Averkiev, HJ Zhai… - The Journal of …, 2011 - pubs.aip.org
We have investigated the structural and electronic properties of the B 17− and B 18− clusters
using photoelectron spectroscopy (PES) and ab initio calculations. The adiabatic electron …

Transition-Metal-Centered Monocyclic Boron Wheel Clusters (M©Bn): A New Class of Aromatic Borometallic Compounds

C Romanescu, TR Galeev, WL Li… - Accounts of chemical …, 2013 - ACS Publications
Atomic clusters have intermediate properties between that of individual atoms and bulk
solids, which provide fertile ground for the discovery of new molecules and novel chemical …

Fluxional boron clusters: from theory to reality

S Pan, J Barroso, S Jalife, T Heine… - Accounts of chemical …, 2019 - ACS Publications
Conspectus Isolated boron clusters exhibit many intriguing properties, which have only
recently been unfolding with the hand-in-hand advancement of state-of-the-art experimental …