Playing with organic radicals as building blocks for functional molecular materials
The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …
properties of persistent organic radicals but there are a lesser number of reports about their …
Synthetic organic spin chemistry for structurally well-defined open-shell graphene fragments
Graphene, a two-dimensional layer of sp 2-hybridized carbon atoms, can be viewed as a
sheet of benzene rings fused together. Three benzene rings can be combined in three …
sheet of benzene rings fused together. Three benzene rings can be combined in three …
Heterocyclic nanographenes and other polycyclic heteroaromatic compounds: synthetic routes, properties, and applications
Two-dimensionally extended, polycyclic heteroaromatic molecules (heterocyclic
nanographenes) are a highly versatile class of organic materials, applicable as functional …
nanographenes) are a highly versatile class of organic materials, applicable as functional …
High stability and luminescence efficiency in donor–acceptor neutral radicals not following the Aufbau principle
With their unusual electronic structures, organic radical molecules display luminescence
properties potentially relevant to lighting applications; yet, their luminescence quantum yield …
properties potentially relevant to lighting applications; yet, their luminescence quantum yield …
Pancake bonding: an unusual pi‐stacking interaction
M Kertesz - Chemistry–A European Journal, 2019 - Wiley Online Library
A category of parallel π‐stacking interaction, termed pancake bonding, is surveyed. The
main characteristics are: the interaction occurs among radicals with highly delocalized π …
main characteristics are: the interaction occurs among radicals with highly delocalized π …
Pillar [5] arene-based neutral radicals with doublet red emissions and stable chiroptical properties
JF Chen, G Tian, K Liu, N Zhang, N Wang, X Yin… - Organic …, 2022 - ACS Publications
Stable organic radicals with unique luminescence show great importance in
photoelectromagnetic materials. We herein report two unusual radical-based systems (P5N …
photoelectromagnetic materials. We herein report two unusual radical-based systems (P5N …
Stable olympicenyl radicals and their π-dimers
Q **ang, J Guo, J Xu, S Ding, Z Li, G Li… - Journal of the …, 2020 - ACS Publications
An olympicenyl radical, a spin 1/2 hydrocarbon radical with C 2 v symmetry and uneven spin
distribution, remains elusive despite the considerable theoretical research interest. Herein …
distribution, remains elusive despite the considerable theoretical research interest. Herein …
Unveiling Three Interconvertible Redox States of Boraphenalene
CL Deng, KK Hollister, A Molino, BYE Tra… - Journal of the …, 2024 - ACS Publications
Neutral 1-boraphenalene displays the isoelectronic structure of the phenalenyl carbocation
and is expected to behave as an attractive organoboron multi-redox system. However, the …
and is expected to behave as an attractive organoboron multi-redox system. However, the …
Phenalenyl‐Based Open‐Shell Polycyclic Aromatic Hydrocarbons
T Kubo - The Chemical Record, 2015 - Wiley Online Library
The phenalenyl radical is a polycyclic aromatic hydrocarbon (PAH) radical. Owing to its
widely distributed spin structure, phenalenyl is relatively stable compared to other …
widely distributed spin structure, phenalenyl is relatively stable compared to other …
Evidence of σ-and π-Dimerization in a Series of Phenalenyls
Phenalenyl and a wide variety of its derivatives form stable radicals, which often associate in
various aggregates with interesting properties that include magnetism and high electrical …
various aggregates with interesting properties that include magnetism and high electrical …