Synthesis of Axially Chiral Monofluoroalkenes via Nickel-Catalyzed Reductive Cross-Coupling of gem-Difluoroalkenes

T Yin, M **, T Zhao, J Chang, D Bai - Organic Letters, 2024 - ACS Publications
Enantioenriched monofluoroalkenes are important structural motifs in life science and
functional materials. To date, only limited strategies were reported for the synthesis of …

Photocatalytic E→ Z isomerization of gem-bromofluoroalkenes: stereoselective synthesis of β-fluorostyrene derivatives

H Kato, Y Kayaki, T Koike - Organic & Biomolecular Chemistry, 2025 - pubs.rsc.org
Stereoselective synthesis of β-fluorostyrene derivatives has been achieved. Selective
isomerization of gem-bromofluoroalkenyl benzenes bearing various ortho-substituents is …