We present here a new example of chemical reactivity governed by quantum tunneling,
which also highlights the limitations of the classical theories. The syn and anti conformers of …

Introducing a small phosphorus-based fragment into other molecular entities via, for
example, phosphorylation/phosphonylation is an important process in synthetic chemistry …

Abstract Nitroso compounds, R–N= O, are common intermediates in organic synthesis, and
are typically amenable to storage and manipulation at ambient temperature under aerobic …

Phosphenic chloride (ClPO2) is an elusive congener of nitryl chloride (ClNO2). By high-
vacuum flash pyrolysis of 2-chloro-1, 3, 2-dioxaphospholane in the gas phase, ClPO2 has …

Trimethyl phosphate (TMP), an organophosphorus compound (OPC), is a promising fire‐
retardant candidate for lithium‐ion battery (LIB) electrolytes to mitigate fire spread. This study …

The vibrational spectra of the simplest phosphaketene HPCO and its isotopologue DPCO in
solid Ar-matrices at 12.0 K have been analyzed with the aid of the computations at the …

Phosphinidenes are heavy congeners of nitrenes that have been broadly used as in situ
reagents in synthetic phosphorus chemistry and also serve as versatile ligands in …

Phosphenic isocyanate (O2PNCO), a novel phosphorus-containing small molecule has
been generated by thermolysis of a dioxaphospholane-based precursor. The …

Phosphorus monoxide (. PO) is a key intermediate in phosphorus chemistry, and its
association with the hydroxyl radical (. OH) to yield metaphosphorous acid (cis‐HOPO) …

The rovibrational spectra of metaphosphorous acid, HOPO, and its deuterated isotopologue
have been studied by vibrational configuration interaction calculations, relying on the …