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Polyoxometalates (POMs): from electroactive clusters to energy materials
Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous
promise for a range of energy-related applications. Their promise is owing to their “special” …
promise for a range of energy-related applications. Their promise is owing to their “special” …
Frontiers of water oxidation: the quest for true catalysts
Development of efficient and economic water oxidation catalysts (WOCs) remains a crucial
bottleneck on the way to artificial photosynthesis applications. Over the past few decades …
bottleneck on the way to artificial photosynthesis applications. Over the past few decades …
Speciation atlas of polyoxometalates in aqueous solutions
Speciation is the key parameter in solution chemistry that describes the composition,
concentration, and oxidation state of each chemical form of an element present in a sample …
concentration, and oxidation state of each chemical form of an element present in a sample …
A Keggin Polyoxometalate Shows Water Oxidation Activity at Neutral pH: POM@ ZIF‐8, an Efficient and Robust Electrocatalyst
Keggin‐type polyoxometalate anions [XM12O40] n− are versatile, as their applications in
interdisciplinary areas show. The Keggin anion [CoW12O40] 6− turns into an efficient and …
interdisciplinary areas show. The Keggin anion [CoW12O40] 6− turns into an efficient and …
The reactivity and stability of polyoxometalate water oxidation electrocatalysts
This review describes major advances in the use of functionalized molecular metal oxides
(polyoxometalates, POMs) as water oxidation catalysts under electrochemical conditions …
(polyoxometalates, POMs) as water oxidation catalysts under electrochemical conditions …
Electrochemically Driven Water-Oxidation Catalysis Beginning with Six Exemplary Cobalt Polyoxometalates: Is It Molecular, Homogeneous Catalysis or Electrode …
A series of six exemplary cobalt-polyoxometalate (Co-POM) precatalysts have been
examined to determine if they are molecular water-oxidation catalysts (WOCatalysts) or if …
examined to determine if they are molecular water-oxidation catalysts (WOCatalysts) or if …
Electrochemical Water Oxidation Catalysis Beginning with Co(II) Polyoxometalates: The Case of the Precatalyst Co4V2W18O6810–
SJ Folkman, RG Finke - ACS Catalysis, 2017 - ACS Publications
The question is addressed of whether the cobalt polyoxometalate (Co-POM) precatalyst
Co4V2W18O6810–(hereafter Co 4 V 2 W 18) is a stable, homogeneous water oxidation …
Co4V2W18O6810–(hereafter Co 4 V 2 W 18) is a stable, homogeneous water oxidation …
Structurally precise two-transition-metal water oxidation catalysts: Quantifying adjacent 3d metals by synchrotron X-radiation anomalous dispersion scattering
Mixed 3d metal oxides are some of the most promising water oxidation catalysts (WOCs), but
it is very difficult to know the locations and percent occupancies of different 3d metals in …
it is very difficult to know the locations and percent occupancies of different 3d metals in …
Self-assembly of a unique triangle-like tungstovanadate containing pentagonal {(WO 7) W 3 (SnR) 2} cluster
HT Zhu, Y Sun, F Su, YJ Zhang, XJ Sang, J Ren… - Dalton …, 2024 - pubs.rsc.org
In aqueous solution, a novel triangle-like tungstovanadate estertin derivative K10H10. 5
[(W4O15 (H2O) 2){(SnCH2CH2COO) 2 (V0. 75W10. 75/V0. 25O39)}{{(SnCH2CH2COO) 2 (μ …
[(W4O15 (H2O) 2){(SnCH2CH2COO) 2 (V0. 75W10. 75/V0. 25O39)}{{(SnCH2CH2COO) 2 (μ …
Synthesis and Characterization of 0D–3D Copper-Containing Tungstobismuthates Obtained from the Lacunary Precursor Na9[B-α-BiW9O33]
KD von Allmen, H Grundmann, A Linden… - Inorganic …, 2017 - ACS Publications
The reaction of the lacunary polyoxometalate precursor Na9 [B-α-BiW9O33]· 19.5 H2O with
Cu (II) ions was explored in search of new economic ways to copper tungstobismuthates as …
Cu (II) ions was explored in search of new economic ways to copper tungstobismuthates as …