Transition-metal-catalyzed direct Csingle bondH functionalization utilizing unsaturated
hydrocarbons have been established as a robust strategy to increase molecular complexity …

An unprecedented Pd‐catalyzed fluorinative bifunctionalization of aziridines and azetidines
was successfully developed via regioselective C− C and C− F bond cleavage of gem …

Here, we report an asymmetric electrochemical organonickel-catalyzed reductive cross-
coupling of aryl aziridines with aryl iodides in an undivided cell, affording β …

Conspectus In recent years, our research group has dedicated significant effort to the field of
asymmetric organometallic electrochemical synthesis (AOES), which integrates …

The development of innovative strategies for the synthesis of N-heterocyclic compounds is
an important topic in organic synthesis. Ring expansion methods to form large N …

Herein, we report the first example of a highly enantioselective alkylative aziridine ring
opening. Under the catalysis of a chiral nickel/pyridine-imidazoline complex, asymmetric C …

Modulating the reaction selectivity is highly attractive and pivotal to the rational design of
synthetic regimes. The defluorinative functionalization of gem-difluorocyclopropanes …

β-Amino sulfones find extensive applications in pharmaceuticals, natural products,
agrochemicals, and organic synthesis. Meanwhile, aziridine units are recognized as …

Aldehydes and aziridines are both intrinsic electrophilic reagents, and thus the coupling
reaction between these two compounds is highly challenging. In this protocol, the merger of …

A transition metal-free, atom-economical, and highly stereospecific synthetic approach to
Friedel–Crafts-type alkylation of arenes/heteroarenes has been developed. The protocol …