Chiral supramolecular polymers

F García, R Gómez, L Sánchez - Chemical Society Reviews, 2023 - pubs.rsc.org
As an active branch within the field of supramolecular polymers, chiral supramolecular
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …

Supramolecular polymerization through kinetic pathway control and living chain growth

M Wehner, F Würthner - Nature Reviews Chemistry, 2020 - nature.com
Supramolecular polymers exhibit fascinating structures, and their properties, and thus
applications, depend both on the strength and dynamics of the non-covalent bonds and on …

Emerging applications for living crystallization-driven self-assembly

L MacFarlane, C Zhao, J Cai, H Qiu, I Manners - Chemical Science, 2021 - pubs.rsc.org
The use of crystallization as a tool to control the self-assembly of polymeric and molecular
amphiphiles in solution is attracting growing attention for the creation of non-spherical …

Controlling supramolecular chirality in multicomponent self-assembled systems

P **ng, Y Zhao - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Chirality exists as a ubiquitous phenomenon in nature, from molecular level l-
amino acids, d-sugar, secondary structures of proteins, DNA, RNA, and nanoscale helices to …

Self-sorted, random, and block supramolecular copolymers via sequence controlled, multicomponent self-assembly

A Sarkar, R Sasmal, C Empereur-Mot… - Journal of the …, 2020 - ACS Publications
Multicomponent supramolecular copolymerization promises to construct complex
nanostructures with emergent properties. However, even with two monomeric components …

Pathway Control of π‐Conjugated Supramolecular Polymers by Incorporating Donor‐Acceptor Functionality

F Wang, R Liao, F Wang - Angewandte Chemie, 2023 - Wiley Online Library
Controlling the nanoscale orientation of π‐conjugated systems remains challenging due to
the complexity of multiple energy landscapes involved in the supramolecular assembly …

Controlling the length of porphyrin supramolecular polymers via coupled equilibria and dilution-induced supramolecular polymerization

E Weyandt, L Leanza, R Capelli, GM Pavan… - Nature …, 2022 - nature.com
Multi-component systems often display convoluted behavior, pathway complexity and
coupled equilibria. In recent years, several ways to control complex systems by manipulating …

Supramolecular polymers–we've come full circle

T Aida, EW Meijer - Israel Journal of Chemistry, 2020 - Wiley Online Library
Since the first polymers were discovered, scientists have debated their structures. Before
Hermann Staudinger published the brilliant concept of macromolecules, polymer properties …

Chirality-controlled supramolecular donor–acceptor copolymerization with distinct energy transfer efficiency

R Liao, F Wang, Y Guo, Y Han… - Journal of the American …, 2022 - ACS Publications
Chirality delivers substantial value to the field of supramolecular polymers, not only serving
as a probe to monitor the dynamic assembly process but providing access to chiroptical …

Pathway complexity in supramolecular copolymerization and blocky star copolymers by a hetero-seeding effect

P Khanra, AK Singh, L Roy, A Das - Journal of the American …, 2023 - ACS Publications
This study unravels the intricate kinetic and thermodynamic pathways involved in the
supramolecular copolymerization of the two chiral dipolar naphthalene monoimide (NMI) …