Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

Catalysis as an enabling science for sustainable polymers

X Zhang, M Fevre, GO Jones, RM Waymouth - Chemical reviews, 2018 - ACS Publications
The replacement of current petroleum-based plastics with sustainable alternatives is a
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …

Polymerization of ethylene oxide, propylene oxide, and other alkylene oxides: synthesis, novel polymer architectures, and bioconjugation

J Herzberger, K Niederer, H Pohlit, J Seiwert… - Chemical …, 2016 - ACS Publications
The review summarizes current trends and developments in the polymerization of alkylene
oxides in the last two decades since 1995, with a particular focus on the most important …

Ring-opening copolymerization of epoxides and cyclic anhydrides with discrete metal complexes: structure–property relationships

JM Longo, MJ Sanford, GW Coates - Chemical reviews, 2016 - ACS Publications
Polyesters synthesized through the alternating copolymerization of epoxides and cyclic
anhydrides compose a growing class of polymers that exhibit an impressive array of …

Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates

S Paul, Y Zhu, C Romain, R Brooks, PK Saini… - Chemical …, 2015 - pubs.rsc.org
Controlled routes to prepare polyesters and polycarbonates are of interest due to the
widespread application of these materials and the opportunities provided to prepare new …

Carbon dioxide (CO 2) as sustainable feedstock for polyurethane production

J Langanke, A Wolf, J Hofmann, K Böhm… - Green …, 2014 - pubs.rsc.org
A dream comes true: tailor-made polyethercarbonate polyols are synthesised from
propylene oxide and CO2. Molecular weight and functionality of these polyethercarbonate …

Evolution of Copolymers of Epoxides and CO2: Catalysts, Monomers, Architectures, and Applications

GW Yang, R **e, YY Zhang, CK Xu, GP Wu - Chemical Reviews, 2024 - ACS Publications
The copolymerization of CO2 and epoxides presents a transformative approach to
converting greenhouse gases into aliphatic polycarbonates (CO2-PCs), thereby reducing …

Self-switchable polymerization: a smart approach to sequence-controlled degradable copolymers

C Hu, X Pang, X Chen - Macromolecules, 2022 - ACS Publications
In the quest for sustainable development, degradable polymers are attractive alternatives to
traditional fossil-based plastics. As monocomponent degradable polymers often suffer from …

Chemoselective polymerizations from mixtures of epoxide, lactone, anhydride, and carbon dioxide

C Romain, Y Zhu, P Dingwall, S Paul… - Journal of the …, 2016 - ACS Publications
Controlling polymer composition starting from mixtures of monomers is an important, but
rarely achieved, target. Here a single switchable catalyst for both ring-opening …

Triethylborane-Assisted Synthesis of Random and Block Poly(ester-carbonate)s through One-Pot Terpolymerization of Epoxides, CO2, and Cyclic Anhydrides

VK Chidara, SK Boopathi, N Hadjichristidis… - …, 2021 - ACS Publications
Poly (ester-carbonate) copolymers were synthesized through triethylborane (TEB)-activated,
one-pot copolymerization of epoxides with anhydrides (AH) and CO2. Depending upon the …