Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Molcas 8: New capabilities for multiconfigurational quantum chemical calculations across the periodic table

F Aquilante, J Autschbach, RK Carlson, LF Chibotaru… - 2016 - Wiley Online Library
In this report, we summarize and describe the recent unique updates and additions to the
Molcas quantum chemistry program suite as contained in release version 8. These updates …

Playing with organic radicals as building blocks for functional molecular materials

I Ratera, J Veciana - Chemical Society Reviews, 2012 - pubs.rsc.org
The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …

Lanthanides in molecular magnetism: old tools in a new field

L Sorace, C Benelli, D Gatteschi - Chemical Society Reviews, 2011 - pubs.rsc.org
In this tutorial review we discuss some basic aspects concerning the magnetic properties of
rare-earth ions, which are currently the subject of a renovated interest in the field of …

Review of purely 4f and mixed-metal nd-4f single-molecule magnets containing only one lanthanide ion

HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2014 - Elsevier
A very basic tutorial-style introduction to Single-Molecule Magnetism, intended for a general
chemistry audience, is provided. This is followed by a review of the synthesis, structures and …

Understanding the magnetic anisotropy toward single-ion magnets

YS Meng, SD Jiang, BW Wang… - Accounts of chemical …, 2016 - ACS Publications
Conspectus Single-molecule magnets (SMMs) can retain their magnetization status
preferentially after removal of the magnetic field below a certain temperature. The unique …

An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes

NF Chilton, D Collison, EJL McInnes… - Nature …, 2013 - nature.com
Understanding the anisotropic electronic structure of lanthanide complexes is important in
areas as diverse as magnetic resonance imaging, luminescent cell labelling and quantum …

[PDF][PDF] Magnetic anisotropy in a dysprosium/DOTA single‐molecule magnet: beyond simple magneto‐structural correlations

G Cucinotta, M Perfetti, J Luzon, M Etienne… - Angewandte Chemie …, 2012 - academia.edu
Lanthanides are strategic materials in current technology [1] and play a remarkable role in
magnetism thanks to their large magnetic moments and large anisotropy.[2] Molecular …

Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets

AB Canaj, S Dey, ER Martí, C Wilson… - Angewandte Chemie …, 2019 - Wiley Online Library
Following a novel synthetic strategy where the strong uniaxial ligand field generated by the
Ph3SiO−(Ph3SiO−= anion of triphenylsilanol) and the 2, 4‐di‐tBu‐PhO−(2, 4‐di‐tBu‐PhO …