A homogeneous manganese‐catalyzed cross‐coupling of two secondary alcohols for the
divergent synthesis of γ‐disubstituted alcohols and β‐disubstituted ketones is reported …

Acyl ureas are a well-known class of organic compounds that have drawn a lot of attention
recently because of their array of chemical properties and possible multi-use in medicine …

The direct functionalization of unactivated organic moieties via C–C bond formation has long
fascinated synthetic chemists. Although base-metal systems are steadily emerging in this …

Polyethyleneimines find many applications in products such as detergents, adhesives,
cosmetics, and for processes such as tissue culture, gene therapy, and CO2 capture. The …

Noble metal catalysts are generally expensive, and thus, abundant 3d metals recently
received significant attention as catalysts in catalytic hydrogenation. Mn catalysts are widely …

Catalytic dehydrogenation, which exhibits highly atom-economical and chemo-selective
properties, converts multiple green sustainable alcohols to critical molecules and is a highly …

Urea derivatives, polyureas, and poly (urea-urethanes) are materials of great interest.
However, their current methods of synthesis involve toxic feedstocks–isocyanate and …

This study introduces a novel polyurethane (PU) synthesis approach, aiming to eliminate the
health risks associated with conventional methods using isocyanates and phosgene …

Electrochemical urea synthesis via the coreduction of CO2 and NO3–is a sustainable
alternative to the traditional Bosch–Meiser process. However, the sluggish reaction kinetics …

A new strategy for the synthesis of unsymmetrical ureas, carbamates, thiocarbamates, and
anilides was developed with methyl pyruvate oxime as the carbonyl synthon. The intrinsic …