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Dynamic covalent synthesis
Dynamic covalent synthesis aims to precisely control the assembly of simple building blocks
linked by reversible covalent bonds to generate a single, structurally complex, product. In …
linked by reversible covalent bonds to generate a single, structurally complex, product. In …
Planar, curved and twisted molecular nanographenes: Reduction-induced alkali metal coordination
Planar and curved polycyclic aromatic hydrocarbons (PAHs) attract significant attention as
molecular models of fullerenes, carbon nanotubes, and graphene, thus stimulating broad …
molecular models of fullerenes, carbon nanotubes, and graphene, thus stimulating broad …
Chiral covalent organic cages: structural isomerism and enantioselective catalysis
Covalent organic cages are a prominent class of discrete porous architectures; however,
their structural isomerism remains relatively unexplored. Here, we demonstrate the structural …
their structural isomerism remains relatively unexplored. Here, we demonstrate the structural …
Self-similar chiral organic molecular cages
Z Wang, QP Zhang, F Guo, H Ma, ZH Liang… - Nature …, 2024 - nature.com
The endeavor to enhance utility of organic molecular cages involves the evolution of them
into higher-level chiral superstructures with self-similar, presenting a meaningful yet …
into higher-level chiral superstructures with self-similar, presenting a meaningful yet …
Highly strained oxygen‐doped chiral molecular belts of the zigzag‐type with strong circularly polarized luminescence
JH Chen, ZY Jiang, H **ao, S Tong… - Angewandte Chemie …, 2023 - Wiley Online Library
Herein we report a two‐directional cyclization strategy for the synthesis of highly strained
depth‐expanded oxygen‐doped chiral molecular belts of the zigzag‐type. From the easily …
depth‐expanded oxygen‐doped chiral molecular belts of the zigzag‐type. From the easily …
[1, 4] Diazocine-Embedded Electron-Rich Nanographenes with Cooperatively Dynamic Skeletons
Curved nanographenes (NGs) are emerging as promising candidates for organic
optoelectronics, supramolecular materials, and biological applications. Here we report a …
optoelectronics, supramolecular materials, and biological applications. Here we report a …
A Triply [5] Helicene‐Bridged (1, 3, 5) Cyclophane
F Aribot, A Merle, P Dechambenoit… - Angewandte Chemie …, 2023 - Wiley Online Library
A rigid propeller‐shaped conjugated triple macrocycle consisting of two nearly perfectly
stacked benzene rings and three linking [5] helicene moieties has been synthesized using a …
stacked benzene rings and three linking [5] helicene moieties has been synthesized using a …
High‐Yielding Nanobelt Formation by Chirality‐Assisted Synthesis
Shape‐persistent conjugated nanobelts (CNBs) are fascinating synthetic targets. However,
in most cases these are made in low overall yields by applying strategies of …
in most cases these are made in low overall yields by applying strategies of …
Cagearenes: synthesis, characterization, and application for programmed vapour release
Here, we announce the establishment of a new family of organic molecular cages, named
cagearenes, by taking advantage of a versatile strategy. These cagearenes were prepared …
cagearenes, by taking advantage of a versatile strategy. These cagearenes were prepared …
A donor–acceptor cage for circularly polarized TADF emission
L Chen, C Li, ZF Liu, Y Kuboi, E Fu… - Chemical …, 2024 - pubs.rsc.org
Herein, we report the first example of chiral donor–acceptor cage DA-2 displaying efficient
circularly polarized thermally activated delayed fluorescence (CP-TADF) with| glum| values …
circularly polarized thermally activated delayed fluorescence (CP-TADF) with| glum| values …