[HTML][HTML] The breaking of symmetry leads to chirality in cucurbituril-type hosts
R Aav, KA Mishra - Symmetry, 2018 - mdpi.com
Cucurbituril-type hosts are highly symmetric, but there are means to break their symmetry.
This review will present examples from three directions of induction of chirality in or by …
This review will present examples from three directions of induction of chirality in or by …
Size‐Control by Anion Templating in Mechanochemical Synthesis of Hemicucurbiturils in the Solid State
S Kaabel, RS Stein, M Fomitšenko… - Angewandte Chemie …, 2019 - Wiley Online Library
Self‐organization is one of the most intriguing phenomena of chemical matter. While the self‐
assembly of macrocycles and cages in dilute solutions has been extensively studied, it …
assembly of macrocycles and cages in dilute solutions has been extensively studied, it …
Merging Bambus [6] uril and Biotin [6] uril into an Enantiomerically Pure Monofunctionalized Hybrid Macrocycle
A Del Mauro, J Lapešová, C Rando… - Organic …, 2023 - ACS Publications
Bambus [6] urils and biotin [6] urils are macrocycles with an exceptional affinity for inorganic
anions. Here, we investigated statistical condensation of 2, 4-dibenzylglycoluril and d-biotin …
anions. Here, we investigated statistical condensation of 2, 4-dibenzylglycoluril and d-biotin …
Stochastic Sensing of Chloride Anions Using an α‐Hemolysin Pore with a semiaza‐Bambusuril Adapter
Pores containing molecular adapters provide internal selective binding sites, thereby
allowing the stochastic sensing of analytes. Herein, we demonstrate that semiaza …
allowing the stochastic sensing of analytes. Herein, we demonstrate that semiaza …
Selective Perchlorate Sensing Using Electrochemical Impedance Spectroscopy with Self‐Assembled Monolayers of semiaza‐Bambusurils
In the last two decades, perchlorate salts have been identified as environmental pollutants
and recognized as potential substances affecting human health. We describe self …
and recognized as potential substances affecting human health. We describe self …
Monofunctionalized Bambus [6] urils and Their Conjugates with Crown Ethers for Liquid–Liquid Extraction of Inorganic Salts
K Maršálek, V Šindelář - Organic letters, 2020 - ACS Publications
Bambusurils are a growing family of macrocyclic anion receptors. In this Letter, we present
the first syntheses of monofunctionalized bambusurils and their use for the preparation of …
the first syntheses of monofunctionalized bambusurils and their use for the preparation of …
Intramolecular van der Waals Interactions Challenge Anion Binding in perthio‐Bambusurils
Bambusurils (BUs) are known to be rigid cavitands that feature an extended, jigger‐like
conformation, and the BU [6] s strongly bind anions within their hydrophobic cavity. These …
conformation, and the BU [6] s strongly bind anions within their hydrophobic cavity. These …
Functionalized Chiral Bambusurils: Synthesis and Host‐Guest Interactions with Chiral Carboxylates
J Sokolov, A Štefek, V Šindelář - ChemPlusChem, 2020 - Wiley Online Library
Bambusurils are a class of macrocyclic anion receptors that exhibit notable anion
recognition properties, able to bind various inorganic anions as well the carboxylates or …
recognition properties, able to bind various inorganic anions as well the carboxylates or …
Reversing selectivity of bambusuril macrocycles toward inorganic anions by installing spacious substituents on their portals
C Rando, S Grewal, J Sokolov, P Kulhánek… - Chemical …, 2025 - pubs.rsc.org
Two chiral bambusurils, which are diastereomers to each other, show remarkable
differences in their binding affinity and selectivity toward inorganic anions as determined by …
differences in their binding affinity and selectivity toward inorganic anions as determined by …
Cyclohexanohemicucurbit [8] uril Inclusion Complexes With Heterocycles and Selective Extraction of Sulfur Compounds From Water
Solid-phase extraction that utilizes selective macrocyclic receptors can serve as a useful tool
for removal of chemical wastes. Hemicucurbiturils are known to form inclusion complexes …
for removal of chemical wastes. Hemicucurbiturils are known to form inclusion complexes …