From glycals to aminosugars: a challenging test for new stereoselective aminohydroxylation and related methodologies
S Mirabella, F Cardona, A Goti - Organic & Biomolecular Chemistry, 2016 - pubs.rsc.org
The introduction of amino functionalities in a regio-and stereoselective manner onto sugar
scaffolds represents a great challenge in carbohydrate synthesis. The most relevant …
scaffolds represents a great challenge in carbohydrate synthesis. The most relevant …
Site selective gold (I)-catalysed benzylic C–H amination via an intermolecular hydride transfer to triazolinediones
Triazolinediones are known as highly reactive dienophiles that can also act as electrophilic
amination reagents towards enolisable C–H bonds (ionic pathway) or weak C–H bonds …
amination reagents towards enolisable C–H bonds (ionic pathway) or weak C–H bonds …
Nickel-Catalyzed Dearomative trans-1,2-Carboamination
LW Hernandez, U Klöckner, J Pospech… - Journal of the …, 2018 - ACS Publications
We describe the development of an arenophile-mediated, nickel-catalyzed dearomative
trans-1, 2-carboamination protocol. A range of readily available aromatic compounds was …
trans-1, 2-carboamination protocol. A range of readily available aromatic compounds was …
Palladium-Catalyzed Dearomative syn-1,4-Carboamination
A dearomative 1, 4-carboamination of arenes has been achieved using arenophile
cycloaddition and subsequent palladium-catalyzed substitution with nonstabilized lithium …
cycloaddition and subsequent palladium-catalyzed substitution with nonstabilized lithium …
Diels–Alder and ene reactions of singlet oxygen, nitroso compounds and triazolinediones: transition states and mechanisms from contemporary theory
Singlet oxygen, nitroso compounds and triazolinediones have similar electronic structures:
they share a low lying LUMO, making them powerful electrophiles, and a high lying HOMO …
they share a low lying LUMO, making them powerful electrophiles, and a high lying HOMO …
Palladium-Catalyzed Dearomative syn-1,4-Diamination
Herein we report a dearomative syn-1, 4-diamination protocol using simple nonactivated
arenes and amines. This one-pot method utilizes arene–arenophile para-cycloadducts …
arenes and amines. This one-pot method utilizes arene–arenophile para-cycloadducts …
Palladium‐Catalyzed Dearomative syn‐1,4‐Carboamination with Grignard Reagents
A protocol for palladium‐catalyzed dearomative functionalization of simple, nonactivated
arenes with Grignard reagents has been established. This one‐pot method features a visible …
arenes with Grignard reagents has been established. This one‐pot method features a visible …
Arenophile-mediated dearomative functionalization strategies
The dearomatization of arenes is a fundamental synthetic strategy, providing a direct
connection between simple hydrocarbons and valuable, more complex intermediates. While …
connection between simple hydrocarbons and valuable, more complex intermediates. While …
Dynamic Covalent Chemistry: A Facile Room‐Temperature, Reversible, Diels–Alder Reaction between Anthracene Derivatives and N‐Phenyltriazolinedione
N Roy, JM Lehn - Chemistry–An Asian Journal, 2011 - Wiley Online Library
A series of readily accessible, dynamic Diels–Alder reactions that are reversible at room
temperature have been developed between anthracene derivatives as dienes and N‐phenyl …
temperature have been developed between anthracene derivatives as dienes and N‐phenyl …
Synthesis of Carbamates from Diethoxycarbonyl Hydrazine Derivatives by E1cB Eliminative Cleavage of the N−N′-Bond Rather than Reduction
P Magnus, N Garizi, KA Seibert, A Ornholt - Organic Letters, 2009 - ACS Publications
Synthesis of Carbamates from Diethoxycarbonyl Hydrazine Derivatives by E1cB Eliminative
Cleavage of the N−N′-Bond Rather than Reduction | Organic Letters ACS ACS Publications …
Cleavage of the N−N′-Bond Rather than Reduction | Organic Letters ACS ACS Publications …