Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021‏ - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Applications of halogen-atom transfer (XAT) for the generation of carbon radicals in synthetic photochemistry and photocatalysis

F Juliá, T Constantin, D Leonori - Chemical Reviews, 2021‏ - ACS Publications
The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …

Enantioselective radical reactions using chiral catalysts

S Mondal, F Dumur, D Gigmes, MP Sibi… - Chemical …, 2022‏ - ACS Publications
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis

MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021‏ - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

Nickel-catalyzed enantioselective electrochemical reductive cross-coupling of aryl aziridines with alkenyl bromides

X Hu, I Cheng-Sánchez… - Journal of the …, 2023‏ - ACS Publications
An electrochemically driven nickel-catalyzed enantioselective reductive cross-coupling of
aryl aziridines with alkenyl bromides has been developed, affording enantioenriched β-aryl …

Stereoselective amino acid synthesis by synergistic photoredox-pyridoxal radical biocatalysis

L Cheng, D Li, BK Mai, Z Bo, L Cheng, P Liu, Y Yang - Science, 2023‏ - science.org
Develo** synthetically useful enzymatic reactions that are not known in biochemistry and
organic chemistry is an important challenge in biocatalysis. Through the synergistic merger …

Photoinduced cobalt-catalyzed desymmetrization of dialdehydes to access axial chirality

H Jiang, XK He, X Jiang, W Zhao, LQ Lu… - Journal of the …, 2023‏ - ACS Publications
Enantioselective metallaphotoredox catalysis, which combines photoredox catalysis and
asymmetric transition-metal catalysis, has become an effective approach to achieve …

Nickel-catalyzed enantioselective reductive cross-coupling reactions

KE Poremba, SE Dibrell, SE Reisman - ACS catalysis, 2020‏ - ACS Publications
Nickel-catalyzed reductive cross-coupling reactions have emerged as powerful methods to
join two electrophiles. These reactions have proven particularly useful for the coupling of sec …

Recent advances in Mn, Fe, Co, and Ni-catalyzed organic reactions

LJ Li, Y He, Y Yang, J Guo, Z Lu, C Wang… - CCS …, 2024‏ - chinesechemsoc.org
This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

A toolbox approach to construct broadly applicable metal-free catalysts for photoredox chemistry: deliberate tuning of redox potentials and importance of halogens in …

E Speckmeier, TG Fischer, K Zeitler - Journal of the American …, 2018‏ - ACS Publications
The targeted choice of specific photocatalysts has been shown to play a critical role for the
successful realization of challenging photoredox catalytic transformations. Herein, we …