Ni-rich layered cathodes for lithium-ion batteries: From challenges to the future

J Yang, X Liang, HH Ryu, CS Yoon, YK Sun - Energy Storage Materials, 2023 - Elsevier
Extending the limited driving range of current electric vehicles (EVs) necessitates the
development of high-energy-density lithium-ion batteries (LIBs) for which Ni-rich layered …

Challenges and strategies towards single‐crystalline Ni‐Rich layered cathodes

L Ni, S Zhang, A Di, W Deng, G Zou… - Advanced energy …, 2022 - Wiley Online Library
The ever‐increasing energy density requirements in electric vehicles (EVs) have boosted
the development of Ni‐rich layered oxide cathodes for state‐of‐the‐art lithium‐ion batteries …

Mitigating Planar Gliding in Single‐Crystal Nickel‐Rich Cathodes through Multifunctional Composite Surface Engineering

Q Zhang, Y Chu, J Wu, P Dong, Q Deng… - Advanced Energy …, 2024 - Wiley Online Library
Nickel‐rich layered oxides are a class of promising cathodes for high‐energy‐density lithium‐
ion batteries (LIBs). However, their structural instability derived from crystallographic planar …

A gradient oxy-thiophosphate-coated Ni-rich layered oxide cathode for stable all-solid-state Li-ion batteries

J Liang, Y Zhu, X Li, J Luo, S Deng, Y Zhao… - Nature …, 2023 - nature.com
High-energy Ni-rich layered oxide cathode materials such as LiNi0. 8Mn0. 1Co0. 1O2
(NMC811) suffer from detrimental side reactions and interfacial structural instability when …

In situ inorganic conductive network formation in high-voltage single-crystal Ni-rich cathodes

X Fan, X Ou, W Zhao, Y Liu, B Zhang, J Zhang… - Nature …, 2021 - nature.com
High nickel content in LiNixCoyMnzO2 (NCM, x≥ 0.8, x+ y+ z= 1) layered cathode material
allows high specific energy density in lithium-ion batteries (LIBs). However, Ni-rich NCM …

Unrecoverable lattice rotation governs structural degradation of single-crystalline cathodes

W Huang, T Liu, L Yu, J Wang, T Zhou, J Liu, T Li… - Science, 2024 - science.org
Transitioning from polycrystalline to single-crystalline nickel-rich cathodes has garnered
considerable attention in both academia and industry, driven by advantages of high tap …

Multiscale crystal field effect for high-performance ultrahigh-Ni layered cathode

L Ni, H Chen, J Gao, Y Mei, H Wang, W Deng, G Zou… - ACS …, 2023 - ACS Publications
Further popularization of ultrahigh-Ni layered cathodes for high-energy lithium-ion batteries
(LIBs) is hampered by their grievous structural and interfacial degeneration upon cycling …

Origin and regulation of oxygen redox instability in high-voltage battery cathodes

X Liu, GL Xu, VSC Kolluru, C Zhao, Q Li, X Zhou, Y Liu… - Nature Energy, 2022 - nature.com
Oxygen redox at high voltage has emerged as a transformative paradigm for high-energy
battery cathodes such as layered transition-metal oxides by offering extra capacity beyond …

A perspective on single-crystal layered oxide cathodes for lithium-ion batteries

J Langdon, A Manthiram - Energy Storage Materials, 2021 - Elsevier
As the demand for lithium-ion batteries grows exponentially to feed the nascent electric-
vehicle and grid-storage markets, the need for higher energy density and longer cycle life …

Enabling structure/interface regulation for high performance Ni‐Rich cathodes

L Ni, H Chen, S Guo, A Dai, J Gao, L Yu… - Advanced Functional …, 2023 - Wiley Online Library
Further commercialization of Ni‐rich layered cathodes is hindered by severe
structure/interface degradation and kinetic hindrance that occur during electrochemical …