Multiblock copolymer synthesis via RAFT emulsion polymerization

GKK Clothier, TR Guimarães, SW Thompson… - Chemical Society …, 2023 - pubs.rsc.org
A multiblock copolymer is a polymer of a specific structure that consists of multiple covalently
linked segments, each comprising a different monomer type. The control of the monomer …

Sequence-and stereo-defined macromolecules: properties and emerging functionalities

R Szweda - Progress in Polymer Science, 2023 - Elsevier
Natural macromolecules, such as proteins and nucleic acids, display various complex
functionalities in biological systems. These functionalities depend on the macromolecular …

[HTML][HTML] Model for disordered proteins with strongly sequence-dependent liquid phase behavior

A Statt, H Casademunt, CP Brangwynne… - The Journal of …, 2020 - pubs.aip.org
Phase separation of intrinsically disordered proteins is important for the formation of
membraneless organelles or biomolecular condensates, which play key roles in the …

[HTML][HTML] Random copolymer membrane coated PBO fibers with significantly improved interfacial adhesion for PBO fibers/cyanate ester composites

T Lin, J Zhang, GU Junwei - Chinese Journal of Aeronautics, 2021 - Elsevier
Abstract Poly (p-phenylene-2, 6-benzobisoxazole)(PBO) fibers possess excellent dielectric,
mechanical properties and heat resistance. However, the surface of PBO fibers is smooth …

The difference between photo-iniferter and conventional RAFT polymerization: high livingness enables the straightforward synthesis of multiblock copolymers

AC Lehnen, JAM Kurki, M Hartlieb - Polymer Chemistry, 2022 - pubs.rsc.org
Photo-iniferter (PI)–RAFT polymerization, the direct activation of chain transfer agents via
light, is a fascinating polymerization technique, as it overcomes some restriction of …

Unsupervised learning of sequence-specific aggregation behavior for a model copolymer

A Statt, DC Kleeblatt, WF Reinhart - Soft matter, 2021 - pubs.rsc.org
We apply a recently developed unsupervised machine learning scheme for local
environments [Reinhart, Comput. Mater. Sci., 2021, 196, 110511] to characterize large …

Isoprene/styrene tapered multiblock copolymers with up to ten blocks: synthesis, phase behavior, order, and mechanical properties

M Steube, T Johann, E Galanos, M Appold… - …, 2018 - ACS Publications
The living anionic copolymerization of isoprene and styrene in cyclohexane affords tapered
block copolymers due to the highly disparate reactivity ratios of r I= 12.8 and r S= 0.051 …

Role of monomer sequence in the crystallization and rheology of PBAT

B Li, W You, L Peng, C Zhang, X Huang, W Yu - Polymer, 2023 - Elsevier
Poly (butylene adipate-ran-terephthalate)(PBAT) is a typical biodegradable aliphatic−
aromatic polyester. It has been widely used as compost bags, packaging films, and …

Recent advances on the structure–properties relationship of multiblock copolymers

GP Baeza - Journal of Polymer Science, 2021 - Wiley Online Library
Multiblock copolymers represent a fascinating class of materials that sits at the very heart of
industrial applications and fundamental polymer science. They are most often made of a …

Sequence-Defined Multiblock Copolymer Nanoengineered Particles from Polymerization-Induced Self-Assembly (PISA): Synthesis and Film Formation

SW Thompson, TR Guimarães, PB Zetterlund - Macromolecules, 2023 - ACS Publications
Multiblock copolymers synthesized via reversible addition–fragmentation transfer (RAFT)
emulsion polymerization offer a pathway to creating new nanoengineered materials …