History repeats itself again: Will the mistakes of the past for ILs be repeated for DESs? From being considered ionic liquids to becoming their alternative: The …

J Afonso, A Mezzetta, IM Marrucho, L Guazzelli - Green Chemistry, 2023 - pubs.rsc.org
The establishment of the place of Deep Eutectic Solvents (DESs) as a new class of green
solvents was essentially grounded on naïve comparisons with Ionic Liquids (ILs), since both …

Replacement of less-preferred dipolar aprotic and ethereal solvents in synthetic organic chemistry with more sustainable alternatives

A Jordan, CGJ Hall, LR Thorp, HF Sneddon - Chemical reviews, 2022 - ACS Publications
Dipolar aprotic and ethereal solvents comprise just over 40% of all organic solvents utilized
in synthetic organic, medicinal, and process chemistry. Unfortunately, many of the common …

[BOK][B] Solvents and solvent effects in organic chemistry

C Reichardt, T Welton - 2011 - books.google.com
Now in its 4th edition, this book remains the ultimate reference for all questions regarding
solvents and solvent effects in organic chemistry. Retaining its proven concept, there is no …

Force field benchmark of organic liquids: density, enthalpy of vaporization, heat capacities, surface tension, isothermal compressibility, volumetric expansion …

C Caleman, PJ Van Maaren, M Hong… - Journal of chemical …, 2012 - ACS Publications
The chemical composition of small organic molecules is often very similar to amino acid side
chains or the bases in nucleic acids, and hence there is no a priori reason why a molecular …

Solvatochromic dyes as solvent polarity indicators

C Reichardt - Chemical reviews, 1994 - ACS Publications
I. Scope This review compiles positively and negatively solvatochromic compounds which
have been usedto establish empirical scales of solvent polarity by means of UV/vis/near-IR …

Solvatochromic parameters for solvents of interest in green chemistry

PG Jessop, DA Jessop, D Fu, L Phan - Green Chemistry, 2012 - pubs.rsc.org
Solvatochromic data have been collected from the literature or newly measured for 83
molecular solvents, 18 switchable solvents, and 187 ionic liquids that have been cited in the …

Late-Stage Halogenation of Complex Substrates with Readily Available Halogenating Reagents

W Wang, S Song, N Jiao - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Late-stage halogenation, targeting specific positions in complex substrates, has
gained significant attention due to its potential for diversifying and functionalizing complex …

Self-assembled π-stacks of functional dyes in solution: structural and thermodynamic features

Z Chen, A Lohr, CR Saha-Möller… - Chemical Society …, 2009 - pubs.rsc.org
This critical review provides an overview on the formation of π-stacks of functional dyes in
solution, aiming to acquaint young researchers with this topical research field and to …

Pyridinium N-Phenolate Betaine Dyes

VG Machado, RI Stock, C Reichardt - Chemical reviews, 2014 - ACS Publications
It is well-known that the solvent can strongly influence the course, rate, and equilibrium
position of many chemical reactions. 1, 2 The position and intensity of the bands in the …

Reference energies for intramolecular charge-transfer excitations

PF Loos, M Comin, X Blase… - Journal of Chemical …, 2021 - ACS Publications
With the aim of completing our previous efforts devoted to local and Rydberg transitions in
organic compounds, we provide a series of highly accurate vertical transition energies for …