The bright future of unconventional σ/π‐hole interactions
Non‐covalent interactions play a crucial role in (supramolecular) chemistry and much of
biology. Supramolecular forces can indeed determine the structure and function of a host …
biology. Supramolecular forces can indeed determine the structure and function of a host …
A million crystal structures: The whole is greater than the sum of its parts
R Taylor, PA Wood - Chemical reviews, 2019 - ACS Publications
The founding in 1965 of what is now called the Cambridge Structural Database (CSD) has
reaped dividends in numerous and diverse areas of chemical research. Each of the million …
reaped dividends in numerous and diverse areas of chemical research. Each of the million …
Electrochemical Azidooxygenation of Alkenes Mediated by a TEMPO–N3 Charge-Transfer Complex
We report a mild and efficient electrochemical protocol to access a variety of vicinally C–O
and C–N difunctionalized compounds from simple alkenes. Detailed mechanistic studies …
and C–N difunctionalized compounds from simple alkenes. Detailed mechanistic studies …
σ‐Hole Interactions in Catalysis
M Breugst, JJ Koenig - European Journal of Organic Chemistry, 2020 - Wiley Online Library
Noncovalent interactions like halogen, chalcogen, and pnictogen bonding are known for a
very long time. During the last decade, these interactions have found different applications in …
very long time. During the last decade, these interactions have found different applications in …
The π-hole revisited
P Politzer, JS Murray, T Clark - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
It follows from the Schrödinger equation that the forces operating within molecules and
molecular complexes are Coulombic, which necessarily entails both electrostatics and …
molecular complexes are Coulombic, which necessarily entails both electrostatics and …
Strength of the pnicogen bond in complexes involving group Va elements N, P, and As
D Setiawan, E Kraka, D Cremer - The Journal of Physical …, 2015 - ACS Publications
A set of 36 pnicogen homo-and heterodimers, R3E··· ER3 and R3E··· E′ R3′, involving
differently substituted group Va elements E= N, P, and As has been investigated at the …
differently substituted group Va elements E= N, P, and As has been investigated at the …
[HTML][HTML] Understanding noncovalent bonds and their controlling forces
S Scheiner - The Journal of Chemical Physics, 2020 - pubs.aip.org
The fundamental underpinnings of noncovalent bonds are presented, focusing on the σ-hole
interactions that are closely related to the H-bond. Different means of assessing their …
interactions that are closely related to the H-bond. Different means of assessing their …
Unprecedented structural variations in trinuclear mixed valence Co (II/III) complexes: Theoretical studies, pnicogen bonding interactions and catecholase-like activities
Three new mixed valence trinuclear Co (II/III) compounds cis-[Co3L2 (MeOH) 2 (N3) 2 (μ1, 1-
N3) 2](1), trans-[Co3L2 (H2O) 2 (N3) 2 (μ1, 1-N3) 2]·(H2O) 2 (2) and [Co3LR2 (N3) 3 (μ1, 3 …
N3) 2](1), trans-[Co3L2 (H2O) 2 (N3) 2 (μ1, 1-N3) 2]·(H2O) 2 (2) and [Co3LR2 (N3) 3 (μ1, 3 …
Directionality of π-holes in nitro compounds
Directionality of π-holes in nitro compounds - Chemical Communications (RSC Publishing)
DOI:10.1039/C4CC09132A Royal Society of Chemistry View PDF VersionPrevious ArticleNext …
DOI:10.1039/C4CC09132A Royal Society of Chemistry View PDF VersionPrevious ArticleNext …
Coordination of anions by noncovalently bonded σ-hole ligands
Research on σ-hole interactions that include halogen, chalcogen, pnicogen, and tetrel
bonding has been accelerating in recent years. These cousins of the H-bond have many …
bonding has been accelerating in recent years. These cousins of the H-bond have many …