Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Atomic-level design of metalloenzyme-like active pockets in metal–organic frameworks for bioinspired catalysis

W Xu, Y Wu, W Gu, D Du, Y Lin, C Zhu - Chemical Society Reviews, 2024 - pubs.rsc.org
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …

Engineering single-atom sites into pore-confined nanospaces of porphyrinic metal–organic frameworks for the highly efficient photocatalytic hydrogen evolution …

Q Mo, L Zhang, S Li, H Song, Y Fan… - Journal of the American …, 2022 - ACS Publications
As a type of heterogeneous catalyst expected for the maximum atom efficiency, a series of
single-atom catalysts (SACs) containing spatially isolated metal single atoms (M-SAs) have …

Energy transfer in metal–organic frameworks for fluorescence sensing

JX Wang, J Yin, O Shekhah, OM Bakr… - … applied materials & …, 2022 - ACS Publications
The development of materials with outstanding performance for sensitive and selective
detection of multiple analytes is essential for the development of human health and society …

Nanoconfinement and mass transport in metal–organic frameworks

CH Sharp, BC Bukowski, H Li, EM Johnson… - Chemical Society …, 2021 - pubs.rsc.org
The ubiquity of metal–organic frameworks in recent scientific literature underscores their
highly versatile nature. MOFs have been developed for use in a wide array of applications …

Metal–organic framework-based materials for wastewater treatment: superior adsorbent materials for the removal of hazardous pollutants

H Kaur, N Devi, SS Siwal, WF Alsanie, MK Thakur… - ACS …, 2023 - ACS Publications
In previous years, different pollutants, for example, organic dyes, antibiotics, heavy metals,
pharmaceuticals, and agricultural pollutants, have been of note to the water enterprise due …

Advances in metal–organic framework-based hydrogel materials: preparation, properties and applications

W Sun, X Zhao, E Webb, G Xu, W Zhang… - Journal of Materials …, 2023 - pubs.rsc.org
Although metal–organic frameworks (MOFs) with intriguing physiochemical properties have
recently attracted increasing attention of researchers, MOFs have not adequately achieved …

Green synthesis of MOF-808 with modulation of particle sizes and defects for efficient phosphate sequestration

Y Tao, B Yang, F Wang, Y Yan, X Hong, H Xu… - Separation and …, 2022 - Elsevier
In this work, a facile and green method is applied to synthesize hydrophilic MOF-808 (Zr)
and modulate its defect content and particle size using different amounts of iron nitrate …

Fibrous Zr‐MOF nanozyme aerogels with macro‐nanoporous structure for enhanced catalytic hydrolysis of organophosphate toxins

K Ma, YH Cheung, KO Kirlikovali, H **e… - Advanced …, 2024 - Wiley Online Library
Metal–organic frameworks (MOFs) with Lewis acid catalytic sites, such as zirconium‐based
MOFs (Zr‐MOFs), comprise a growing class of phosphatase‐like nanozymes that can …

Unveiling Unexpected Modulator-CO2 Dynamics within a Zirconium Metal–Organic Framework

TM Rayder, F Formalik, SM Vornholt… - Journal of the …, 2023 - ACS Publications
Carbon capture, storage, and utilization (CCSU) represents an opportunity to mitigate
carbon emissions that drive global anthropogenic climate change. Promising materials for …