Production of Hydrogen from Alcohols Via Homogeneous Catalytic Transformations by Molecular Transition-Metal Complexes

A Bisarya, S Karim, H Nar**ari, A Banerjee… - Chemical …, 2024 - pubs.rsc.org
Hydrogen obtained from renewable sources such as water and alcohols is regarded as an
efficient clean-burning alternative to non-renewable fuels. The use of the so called bio-H2 …

Guerbet-type β-alkylation of secondary alcohols catalyzed by chromium chloride and its corresponding NNN pincer complex

H Nar**ari, N Tanwar, L Kathuria, RV Jasra… - Catalysis Science & …, 2022 - pubs.rsc.org
The β-alkylation of secondary alcohols has been successfully accomplished using earth
abundant, inexpensive and environmentally benign 3d transition metal chromium salt CrCl3 …

Pincer–ruthenium-catalyzed reforming of methanol─ selective high-yield production of formic acid and hydrogen

V Arora, E Yasmin, N Tanwar, VR Hathwar, T Wagh… - Acs …, 2023 - ACS Publications
A series of NNN pincer–ruthenium complexes of the type (R2NNN) RuCl2 (CH3CN) based
on bis (imino) pyridine ligands were synthesized and characterized. These pincer ruthenium …

Manganese-catalysed dehydrogenative oxidation of glycerol to lactic acid

CQ Deng, J Deng, Y Fu - Green Chemistry, 2022 - pubs.rsc.org
Herein, we report a well-defined pincer manganese complex supported by PNP ligands for
the conversion of glycerol to sodium lactate with dihydrogen liberation. Sodium lactate could …

Reforming of ethanol to hydrogen and acetic acid catalyzed by pincer-ruthenium complexes

V Arora, S Dhole, A Kumar - Catalysis Science & Technology, 2023 - pubs.rsc.org
Ethanol is feed-agnostic and is hence currently one of the most preferred renewable
resources for manufacturing essential industrial commodities globally. Herein, we present …

NNN Pincer-Manganese-Catalyzed Guerbet-Type β-Alkylation of Alcohols under Microwave Irradiation

A Bisarya, RV Jasra, A Kumar - Organometallics, 2023 - ACS Publications
A series of manganese carbonyl complexes based on bis (imino) pyridine ligands of the type
R2NNN (R= Cy, i Pr, Ph, p-FC6H4) were synthesized. While the complex appears to be an …

A review of the catalytic conversion of glycerol to lactic acid in the presence of aqueous base

D Akbulut, S Özkar - RSC advances, 2022 - pubs.rsc.org
Lactic acid is a high-value-added chemical with large production, which is used in many
industries including the production of pyruvic and acrylic acids. Lactic acid is largely …

Microwave-assisted pincer-ruthenium catalyzed Guerbet reaction for the upgradation of bio-ethanol to bio-butanol

K Das, L Kathuria, RV Jasra, S Dhole… - Catalysis Science & …, 2023 - pubs.rsc.org
The upgradation of feed agnostic bio-ethanol to fuel grade n-butanol was accomplished via
the pincer-ruthenium catalyzed Guerbet reaction under microwave irradiation (75 W, 110° C) …

Selective oxidation of glycerol to lactic acid catalyzed by CuO/activated carbon and reaction kinetics

S Li, S Li, Y Wang, C Tang, L Qiu, S Yu - ACS omega, 2024 - ACS Publications
Activated carbon-supported CuO catalysts were prepared by an ammonia evaporation
method and applied to catalyze the selective oxidation of glycerol to lactic acid. The effects …