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Homogeneous vs. heterogeneous catalysts for acceptorless dehydrogenation of biomass-derived glycerol and ethanol towards circular chemistry
The benefits of transitioning to chemical and material circularity are readily apparent.
However, identifying and develo** the necessary chemical transformations for platform …
However, identifying and develo** the necessary chemical transformations for platform …
Production of Hydrogen from Alcohols Via Homogeneous Catalytic Transformations by Molecular Transition-Metal Complexes
Hydrogen obtained from renewable sources such as water and alcohols is regarded as an
efficient clean-burning alternative to non-renewable fuels. The use of the so called bio-H2 …
efficient clean-burning alternative to non-renewable fuels. The use of the so called bio-H2 …
Guerbet-type β-alkylation of secondary alcohols catalyzed by chromium chloride and its corresponding NNN pincer complex
The β-alkylation of secondary alcohols has been successfully accomplished using earth
abundant, inexpensive and environmentally benign 3d transition metal chromium salt CrCl3 …
abundant, inexpensive and environmentally benign 3d transition metal chromium salt CrCl3 …
Pincer–ruthenium-catalyzed reforming of methanol─ selective high-yield production of formic acid and hydrogen
A series of NNN pincer–ruthenium complexes of the type (R2NNN) RuCl2 (CH3CN) based
on bis (imino) pyridine ligands were synthesized and characterized. These pincer ruthenium …
on bis (imino) pyridine ligands were synthesized and characterized. These pincer ruthenium …
Manganese-catalysed dehydrogenative oxidation of glycerol to lactic acid
CQ Deng, J Deng, Y Fu - Green Chemistry, 2022 - pubs.rsc.org
Herein, we report a well-defined pincer manganese complex supported by PNP ligands for
the conversion of glycerol to sodium lactate with dihydrogen liberation. Sodium lactate could …
the conversion of glycerol to sodium lactate with dihydrogen liberation. Sodium lactate could …
Reforming of ethanol to hydrogen and acetic acid catalyzed by pincer-ruthenium complexes
Ethanol is feed-agnostic and is hence currently one of the most preferred renewable
resources for manufacturing essential industrial commodities globally. Herein, we present …
resources for manufacturing essential industrial commodities globally. Herein, we present …
NNN Pincer-Manganese-Catalyzed Guerbet-Type β-Alkylation of Alcohols under Microwave Irradiation
A series of manganese carbonyl complexes based on bis (imino) pyridine ligands of the type
R2NNN (R= Cy, i Pr, Ph, p-FC6H4) were synthesized. While the complex appears to be an …
R2NNN (R= Cy, i Pr, Ph, p-FC6H4) were synthesized. While the complex appears to be an …
A review of the catalytic conversion of glycerol to lactic acid in the presence of aqueous base
Lactic acid is a high-value-added chemical with large production, which is used in many
industries including the production of pyruvic and acrylic acids. Lactic acid is largely …
industries including the production of pyruvic and acrylic acids. Lactic acid is largely …
Microwave-assisted pincer-ruthenium catalyzed Guerbet reaction for the upgradation of bio-ethanol to bio-butanol
The upgradation of feed agnostic bio-ethanol to fuel grade n-butanol was accomplished via
the pincer-ruthenium catalyzed Guerbet reaction under microwave irradiation (75 W, 110° C) …
the pincer-ruthenium catalyzed Guerbet reaction under microwave irradiation (75 W, 110° C) …
Selective oxidation of glycerol to lactic acid catalyzed by CuO/activated carbon and reaction kinetics
S Li, S Li, Y Wang, C Tang, L Qiu, S Yu - ACS omega, 2024 - ACS Publications
Activated carbon-supported CuO catalysts were prepared by an ammonia evaporation
method and applied to catalyze the selective oxidation of glycerol to lactic acid. The effects …
method and applied to catalyze the selective oxidation of glycerol to lactic acid. The effects …