Advanced materials based on polymer cocrystalline forms

G Guerra, C Daniel, P Rizzo… - Journal of Polymer …, 2012 - Wiley Online Library
Polymeric “cocrystalline forms,” that is, structures were a polymeric host and a low‐
molecular‐mass guest are cocrystallized, were early recognized, and in many cases also …

Polymorphism of poly (2, 6-dimethyl-1, 4-phenylene) oxide (PPO): Co-crystalline and nanoporous-crystalline phases

F Auriemma, C Daniel, M Golla, B Nagendra, P Rizzo… - Polymer, 2022 - Elsevier
Relevant information on PPO crystallization, with particular emphasis on nanoporous
crystalline (NC) and related co-crystalline (CC) forms, is reviewed. Preparation methods …

Salicylic acid Release from syndiotactic polystyrene Staple fibers

V Covelli, A Cozzolino, P Rizzo, M Rodriquez… - Molecules, 2023 - mdpi.com
Films and fibers of syndiotactic polystyrene (sPS), being amorphous or exhibiting
nanoporous crystalline (NC) or dense crystalline phases, were loaded with salicylic acid …

Fast uptake of organic pollutants from dilute aqueous solutions by nanoporous-crystalline PPO films with c-perpendicular orientation

A Cozzolino, B Nagendra, P Rizzo, C Daniel… - European Polymer …, 2021 - Elsevier
The extraordinary ability of poly (2, 6-dimethyl-1, 4-phenylene) oxide (PPO) dense films,
exhibiting a nanoporous-crystalline (NC) phase, to absorb traces of organic pollutants …

Nanoporous crystalline phases of poly (2, 6-dimethyl-1, 4-phenylene) oxide

C Daniel, S Longo, G Fasano, JG Vitillo… - Chemistry of …, 2011 - ACS Publications
Crystalline modifications, exhibiting largely different X-ray diffraction patterns, have been
obtained for poly (2, 6-dimethyl-1, 4-phenylene) oxide (PPO), by gel desiccation procedures …

High surface area nanoporous-crystalline polymer films

B Nagendra, A Cozzolino, C Daniel, P Rizzo… - …, 2022 - ACS Publications
Based on a commercially available thermoplastic polymer (poly (2, 6-dimethyl-1, 4-
phenylene) oxide, PPO), nanoporous-crystalline (NC) polymer films with a surface area (SA) …

Monolithic nanoporous crystalline aerogels

C Daniel, S Longo, R Ricciardi… - Macromolecular …, 2013 - Wiley Online Library
Monolithic aerogels can be easily obtained by drying physical gels formed by linear uncross‐
linked polymers. Preparation methods, structure, and properties of these physically cross …

Polymer co-crystallization from LLE: Crystallization kinetics of POCB hydrate from two-phase mixtures of POCB and water

S Banerjee, M Gresh-Sill, EF Barker, TY Meyer… - Polymer, 2023 - Elsevier
Abstract Polyoxacyclobutane (POCB,–[CH 2 CH 2 CH 2 O−] n) has the rare ability to co-
crystallize with water to form a hydrate. Above the melting point of the hydrate (∼ 37° C) …

Monomeric and dimeric carboxylic acid in crystalline cavities and channels of delta and epsilon forms of syndiotactic polystyrene

A Cozzolino, G Monaco, C Daniel, P Rizzo, G Guerra - Polymers, 2021 - mdpi.com
Delta (δ) and epsilon (ε) co-crystalline forms of syndiotactic polystyrene with a carboxylic
acid guest were obtained by sorption of liquid hexanoic acid in syndiotactic polystyrene films …

Linear hydrogen bonded aggregates of carboxylic acids in crystalline channels of syndiotactic polystyrene

A Cozzolino, S Pappalardo, P Rizzo, G Guerra - Polymer, 2022 - Elsevier
Sorption of long aliphatic carboxylic acids (lauric with 12 C atoms and stearic with 18 C
atoms) and of an aliphatic dicarboxylic acid (adipic), by amorphous and nanoporous …