1H-Detected Biomolecular NMR under Fast Magic-Angle Spinning

T Le Marchand, T Schubeis, M Bonaccorsi… - Chemical …, 2022 - ACS Publications
Since the first pioneering studies on small deuterated peptides dating more than 20 years
ago, 1H detection has evolved into the most efficient approach for investigation of …

Solid-state NMR investigations of extracellular matrixes and cell walls of algae, bacteria, fungi, and plants

N Ghassemi, A Poulhazan, F Deligey… - Chemical …, 2021 - ACS Publications
Extracellular matrixes (ECMs), such as the cell walls and biofilms, are important for
supporting cell integrity and function and regulating intercellular communication. These …

Structure of fully protonated proteins by proton-detected magic-angle spinning NMR

LB Andreas, K Jaudzems, J Stanek… - Proceedings of the …, 2016 - National Acad Sciences
Protein structure determination by proton-detected magic-angle spinning (MAS) NMR has
focused on highly deuterated samples, in which only a small number of protons are …

Atomic-resolution chemical characterization of (2x)72-kDa tryptophan synthase via four- and five-dimensional 1H-detected solid-state NMR

A Klein, P Rovó, VV Sakhrani, Y Wang… - Proceedings of the …, 2022 - National Acad Sciences
NMR chemical shifts provide detailed information on the chemical properties of molecules,
thereby complementing structural data from techniques like X-ray crystallography and …

Deuteration for high-resolution detection of protons in protein magic angle spinning (MAS) solid-state NMR

B Reif - Chemical Reviews, 2021 - ACS Publications
Proton detection developed in the last 20 years as the method of choice to study
biomolecules in the solid state. In perdeuterated proteins, proton dipolar interactions are …

Spinning proteins, the faster, the better?

A Böckmann, M Ernst, BH Meier - Journal of Magnetic Resonance, 2015 - Elsevier
Magic-angle spinning (MAS) is a technique that is a prerequisite for high-resolution solid-
state NMR spectroscopy of proteins and other biomolecules. Recently, the 100 kHz limit for …

NMR spectroscopic assignment of backbone and side‐chain protons in fully protonated proteins: microcrystals, sedimented assemblies, and amyloid fibrils

J Stanek, LB Andreas, K Jaudzems… - Angewandte Chemie …, 2016 - Wiley Online Library
We demonstrate sensitive detection of alpha protons of fully protonated proteins by solid‐
state NMR spectroscopy with 100–111 kHz magic‐angle spinning (MAS). The excellent …

High-resolution proton-detected NMR of proteins at very fast MAS

LB Andreas, T Le Marchand, K Jaudzems… - Journal of magnetic …, 2015 - Elsevier
When combined with high-frequency (currently∼ 60 kHz) magic-angle spinning (MAS),
proton detection boosts sensitivity and increases coherence lifetimes, resulting in narrow 1 …

Structure and gating behavior of the human integral membrane protein VDAC1 in a lipid bilayer

EE Najbauer, K Tekwani Movellan… - Journal of the …, 2022 - ACS Publications
The voltage-dependent anion channel (VDAC), the most abundant protein in the outer
mitochondrial membrane, is responsible for the transport of all ions and metabolites into and …

Structure and Mechanism of the Influenza A M218–60 Dimer of Dimers

LB Andreas, M Reese, MT Eddy, V Gelev… - Journal of the …, 2015 - ACS Publications
We report a magic angle spinning (MAS) NMR structure of the drug-resistant S31N mutation
of M218–60 from Influenza A. The protein was dispersed in diphytanoyl-sn-glycero-3 …