Solid-state NMR spectroscopy

B Reif, SE Ashbrook, L Emsley, M Hong - Nature Reviews Methods …, 2021 - nature.com
Solid-state nuclear magnetic resonance (NMR) spectroscopy is an atomic-level method to
determine the chemical structure, 3D structure and dynamics of solids and semi-solids. This …

Surface Structure and Chemistry of CeO2 Powder Catalysts Determined by Surface-Ligand Infrared Spectroscopy (SLIR)

C Yang, H Idriss, Y Wang, C Wöll - Accounts of Chemical …, 2024 - ACS Publications
Conspectus Cerium is the most abundant rare earth element in the Earth's crust. Its most
stable oxide, cerium dioxide (CeO2, ceria), is increasingly utilized in the field of catalysis. It …

Probing the Actual Role and Activity of Oxygen Vacancies in Toluene Catalytic Oxidation: Evidence from In Situ XPS/NEXAFS and DFT + U Calculation

Z Su, X Li, W Si, L Artiglia, Y Peng, J Chen… - ACS …, 2023 - ACS Publications
Metal oxide catalysts like CeO2 exhibit promising prospects to replace the currently used
noble metal catalysts in the catalytic oxidation of volatile organic compounds (VOCs) …

Enhancing ionic conductivity in solid electrolyte by relocating diffusion ions to under-coordination sites

L Zhu, Y Wang, J Chen, W Li, T Wang, J Wu, S Han… - Science …, 2022 - science.org
Solid electrolytes are highly important materials for improving safety, energy density, and
reversibility of electrochemical energy storage batteries. However, it is a challenge to …

Boosting the Catalytic Performance of CeO2 in Toluene Combustion via the Ce–Ce Homogeneous Interface

Z Su, W Si, H Liu, S **ong, X Chu, W Yang… - Environmental …, 2021 - ACS Publications
Catalytic combustion is an advanced technology to eliminate industrial volatile organic
compounds such as toluene. In order to replace the expensive noble metal catalysts and …

Unveiling the Surface Structure of ZnO Nanorods and H2 Activation Mechanisms with 17O NMR Spectroscopy

B Song, Y Li, XP Wu, F Wang, M Lin… - Journal of the …, 2022 - ACS Publications
ZnO plays a very important role in many catalytic processes involving H2, yet the details on
their interactions and H2 activation mechanism are still missing, owing to the lack of a …

Differentiating Surface Ce Species among CeO2 Facets by Solid-State NMR for Catalytic Correlation

Z Tan, G Li, HL Chou, Y Li, X Yi, AH Mahadi… - ACS …, 2020 - ACS Publications
Altering the exposed facet of CeO2 nanocrystallites and hence the control of surface
chemistry on the nano level have been shown to significantly change their performances in …

[HTML][HTML] Vibrational frequencies of CO bound to all three low-index cerium oxide surfaces: A consistent theoretical description of vacancy-induced changes using …

PG Lustemberg, C Yang, Y Wang, C Wöll… - The Journal of …, 2023 - pubs.aip.org
The facet-dependent adsorption of CO on oxidized and reduced CeO 2 single crystal
surfaces is reviewed, with emphasis on the effect of CO coverage and the ability of state-of …

Surface refaceting mechanism on cubic ceria

C Yang, M Capdevila-Cortada, C Dong… - The journal of …, 2020 - ACS Publications
Polar surfaces of solid oxides are intrinsically unstable and tend to reconstruct due to the
diverging electrostatic energy and thus often exhibit unique physical and chemical …

Oxygen-vacancy-rich CeO 2/Ru nanoparticles enable a high-performance catalyst for alkaline hydrogen oxidation

Z Cheng, Y Yang, J Yang, S Chen, P Wang… - Journal of Materials …, 2024 - pubs.rsc.org
A highly active, stable and low-cost platinum-free anode catalyst based on Ru for hydroxide
exchange membrane fuel cells (HEMFCs) is hindered by the strong oxophilicity of Ru, which …