Dissipative formation of covalent basket cages
VW Liyana Gunawardana, TJ Finnegan… - Angewandte …, 2022 - Wiley Online Library
Living systems use chemical fuels to transiently assemble functional structures. As a step
toward constructing abiotic mimics of such structures, we herein describe dissipative …
toward constructing abiotic mimics of such structures, we herein describe dissipative …
From selection to instruction and back: competing conformational selection and induced fit pathways in abiotic hosts
Two limiting cases of molecular recognition, induced fit (IF) and conformational selection
(CS), play a central role in allosteric regulation of natural systems. The IF paradigm states …
(CS), play a central role in allosteric regulation of natural systems. The IF paradigm states …
On the Selectivity in the Synthesis of 3-Fluoropiperidines Using BF3-Activated Hypervalent Iodine Reagents
RZ Pavlović, TJ Kop, M Nesic… - The Journal of …, 2023 - ACS Publications
Fluorinated piperidines find wide applications, most notably in the development of novel
therapies and agrochemicals. Cyclization of alkenyl N-tosylamides promoted by BF3 …
therapies and agrochemicals. Cyclization of alkenyl N-tosylamides promoted by BF3 …
Control and transfer of chirality within well-defined tripodal supramolecular cages
G Qiu, P Nava, C Colomban, A Martinez - Frontiers in Chemistry, 2020 - frontiersin.org
The development of new strategies to turn achiral artificial hosts into highly desirable chiral
receptors is a crucial challenge in order to advance the fields of asymmetric transformations …
receptors is a crucial challenge in order to advance the fields of asymmetric transformations …
Supersensitive detection of anions in pure organic and aqueous media by amino acid conjugated Ellman's reagent
The last few decades witnessed a remarkable advancement in the field of molecular anion
receptors. A variety of anion binding motifs have been discovered, and large number of …
receptors. A variety of anion binding motifs have been discovered, and large number of …
Photoinduced interruption of interannular cooperativity for delivery of cationic guests in water
The synergy among twelve carboxylates from two hexavalent baskets 16− assisted the
encapsulation of one divalent diammonium guest 32+–62+ and the formation of ternary [3 …
encapsulation of one divalent diammonium guest 32+–62+ and the formation of ternary [3 …
A computational study of competing conformational selection and induced fit in an abiotic system
Host–guest complexations can be described by two competing mechanisms, conformational
selection (CS) and induced fit (IF). In this work, we used a combination of nudged elastic …
selection (CS) and induced fit (IF). In this work, we used a combination of nudged elastic …
Rationalization of chirality transfer and fast conformational changes in a tris (2-pyridylmethyl) amine-based cage
The key features that govern the chirality transfer in a structurally contracted covalent cage,
consisting of a northern chiral cyclotriveratrylene (CTV) connected to a southern tris (2 …
consisting of a northern chiral cyclotriveratrylene (CTV) connected to a southern tris (2 …
Bridged benzocyclotrimers: concepts, synthesis, and applications
Bridged polycyclic frameworks represent a unique tool to form curved units; the bicyclo [2.2.
1] hepta-2, 5-diene system is widely exploited to design and induce concave topologies. In …
1] hepta-2, 5-diene system is widely exploited to design and induce concave topologies. In …
A Molecular Capsule with Revolving Doors Partitioning Its Inner Space
Z Lei, TJ Finnegan, VWL Gunawardana… - … A European Journal, 2020 - Wiley Online Library
Covalent capsule 1 was designed to include two molecular baskets linked with three mobile
pyridines tucked into its inner space. On the basis of both theory (DFT) and experiments …
pyridines tucked into its inner space. On the basis of both theory (DFT) and experiments …