Triplet pair states in singlet fission

K Miyata, FS Conrad-Burton, FL Geyer… - Chemical reviews, 2019 - ACS Publications
This account aims at providing an understanding of singlet fission, ie, the photophysical
process of a singlet state (S1) splitting into two triplet states (2× T1) in molecular …

Unconventional singlet fission materials

T Ullrich, D Munz, DM Guldi - Chemical Society Reviews, 2021 - pubs.rsc.org
Singlet fission (SF) is a photophysical downconversion pathway, in which a singlet excitation
transforms into two triplet excited states. As such, it constitutes an exciton multiplication …

Quintet multiexciton dynamics in singlet fission

MJY Tayebjee, SN Sanders, E Kumarasamy… - Nature Physics, 2017 - nature.com
Singlet fission, in which two triplet excitons are generated from a single absorbed photon, is
a key third-generation solar cell concept. Conservation of angular momentum requires that …

Leveraging charge-transfer interactions in through-space-coupled pentacene dendritic oligomer for singlet exciton fission

J Kim, HT Teo, Y Hong, YC Liau, D Yim… - Journal of the …, 2023 - ACS Publications
Singlet exciton fission in organic chromophores has received much attention during the past
decade. Inspired by numerous spectroscopic studies in the solid state, there have been …

Spatial separation of triplet excitons drives endothermic singlet fission

NV Korovina, CH Chang, JC Johnson - Nature Chemistry, 2020 - nature.com
Molecules that undergo singlet fission, converting singlet excitons into pairs of triplet
excitons, have potential as photovoltaic materials. The possible advantages of endothermic …

Crystalline silicon solar cells with tetracene interlayers: the path to silicon-singlet fission heterojunction devices

RW MacQueen, M Liebhaber, J Niederhausen… - Materials …, 2018 - pubs.rsc.org
Singlet exciton fission is an exciton multiplication process that occurs in certain organic
materials, converting the energy of single highly-energetic photons into pairs of triplet …

Identifying triplet pathways in dilute pentacene films

D Lubert-Perquel, E Salvadori, M Dyson… - Nature …, 2018 - nature.com
Building efficient triplet-harvesting layers for photovoltaic applications requires a deep
understanding of the microscopic properties of the components involved and their dynamics …

What next for singlet fission in photovoltaics? The fate of triplet and triplet-pair excitons

RJ Hudson, AN Stuart, DM Huang… - The Journal of Physical …, 2022 - ACS Publications
Exciton multiplication through singlet fission (SF) has the potential to surpass the detailed-
balance efficiency limit of single-junction photovoltaic (PV) devices. However, energy loss …

Singlet fission in concentrated TIPS-pentacene solutions: The role of excimers and aggregates

M Dvořák, SKK Prasad, CB Dover… - Journal of the …, 2021 - ACS Publications
The excited-state dynamics of 6, 13-bis (triisopropylsilylethynyl) pentacene is investigated to
determine the role of excimer and aggregate formation in singlet fission in high …

Singlet-fission-born quintet state: Sublevel selections and trap** by multiexciton thermodynamics

H Nagashima, S Kawaoka, S Akimoto… - The journal of …, 2018 - ACS Publications
Singlet fission (SF) is expected to exceed the theoretical limit of the solar cell efficiency.
Quintet (Q) state generation in triplet–triplet pair is essential for preventing the unwanted …