Among the various characteristics of metal–organic frameworks (MOFs), redox activity, the
ability to store or release electrons is a vital property for functional MOFs in applications like …

Conspectus The directed synthesis and functionalization of porous crystalline materials
pose significant challenges for chemists. The synergistic integration of different …

Single-ion magnets (SIMs) and single-molecule magnets (SMMs) are typically made up of
3d and/or 4f complexes that possess significant energy barriers to prevent the spin reversal …

Host–guest electron transfer (HGET) in molecular framework systems is a critical trigger for
drastic functional changes in both host framework and guest. A reversible magnetic phase …

Near-infrared (NIR) photothermal materials hold great promise for use in several
applications, particularly in photothermal therapy, diagnosis, and imaging. However, current …

Lanthanide metal–organic frameworks (Ln-MOFs) showing single-molecule magnet (SMM)
properties are an ever-growing family of materials where the magnetic properties can be …

Rare earths, scandium, yttrium, and the fifteen lanthanoids from lanthanum to lutetium, are
classified as critical metals because of their ubiquity in daily life. They are present in …

It is still challenging for Dy-MOFs to modulate the single-molecule magnet (SMM) behavior
through guest molecules. Dy-MOFs with different guest molecules, secondary building units …

Modern and upcoming high-speed optoelectronics as well as secure data storage or solar
energy harvesting technologies integrating stimuli-responsive materials fully rely on the …

The chemical immobilization of cobalt (II) ions in a silica aerogel matrix enabled the
synthesis of the first representative example of aerogel-based single-ion magnets. For the …