Isolating single and few atoms for enhanced catalysis

Y Chen, J Lin, B Jia, X Wang, S Jiang… - Advanced …, 2022 - Wiley Online Library
Atomically dispersed metal catalysts have triggered great interest in the field of catalysis
owing to their unique features. Isolated single or few metal atoms can be anchored on …

Antiperovskite electrolytes for solid-state batteries

W **a, Y Zhao, F Zhao, K Adair, R Zhao, S Li… - Chemical …, 2022 - ACS Publications
Solid-state batteries have fascinated the research community over the past decade, largely
due to their improved safety properties and potential for high-energy density. Searching for …

Synthesis of a monolayer fullerene network

L Hou, X Cui, B Guan, S Wang, R Li, Y Liu, D Zhu… - Nature, 2022 - nature.com
Abstract Two-dimensional (2D) carbon materials, such as graphene, have attracted
particular attention owing to the exceptional carrier transport characteristics that arise from …

Platonic and Archimedean solids in discrete metal-containing clusters

XM Luo, YK Li, XY Dong, SQ Zang - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

Pentagon-based 2D materials: Classification, properties and applications

Y Shen, Q Wang - Physics Reports, 2022 - Elsevier
Abstract Since penta-graphene (PG), a two-dimensional (2D) carbon allotrope exclusively
composed of five-membered rings, was proposed in 2015, a great deal of effort has been …

Endohedrally doped cage clusters

J Zhao, Q Du, S Zhou, V Kumar - Chemical Reviews, 2020 - ACS Publications
The discovery of carbon fullerene cages and their solids opened a new avenue to build
materials from stable cage clusters as “artificial atoms” or “superatoms” instead of atoms …

Chemically modified gold/silver superatoms as artificial elements at nanoscale: design principles and synthesis challenges

S Takano, T Tsukuda - Journal of the American Chemical Society, 2021 - ACS Publications
Pure and doped gold/silver clusters protected by monolayers of organic ligands have
attracted much interest as novel functional materials owing to their nonbulk-like, size-specific …

Superatoms in materials science

EA Doud, A Voevodin, TJ Hochuli… - Nature Reviews …, 2020 - nature.com
Clusters are ensembles of bound atoms intermediate in size between a molecule and a bulk
solid. Some of these clusters form stable units with atomically precise structures that give …

Probing the binding and activation of small molecules by gas-phase transition metal clusters via IR spectroscopy

A Fielicke - Chemical Society Reviews, 2023 - pubs.rsc.org
Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …

Iron-cluster-directed synthesis of 2D/2D Fe–N–C/MXene superlattice-like heterostructure with enhanced oxygen reduction electrocatalysis

L Jiang, J Duan, J Zhu, S Chen, M Antonietti - ACS nano, 2020 - ACS Publications
Metal clusters, an emerging category of materials with molecular metal dispersity, have been
proposed for versatile applications. In this work, we show an unexpected function of metal …