Gold(I)‐N‐Heterocyclic Carbene Synthons in Organometallic Synthesis

T Scattolin, G Tonon, E Botter, SG Guillet… - … A European Journal, 2023 - Wiley Online Library
The prominent role of gold‐N‐heterocyclic carbene (NHC) complexes in numerous research
areas such as homogeneous (photo) catalysis, medicinal chemistry and materials science …

Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route

T Scattolin, AA Logvinov, NV Tzouras, CSJ Cazin… - …, 2023 - ACS Publications
N-heterocyclic carbene (NHC) ligands have evolved from being simple lab curiosities to
tertiary phosphine mimics to finally take center stage as unique supporting ligands in …

Mechanochemical tools in the synthesis of organometallic compounds

DV Aleksanyan, VA Kozlov - Mendeleev Communications, 2023 - Elsevier
In response to rising environmental concerns, chemistry is experiencing a considerable
change in both concepts and practices to adopt more efficient and sustainable technologies …

Robust Two-Coordinate Zn (II) Organocations Supported by Bulky-Yet-Flexible IPr* Carbene: Synthesis, Structure, and Distinct Reactivity in Hydrosilylation Catalysis

X Xu, C Gourlaouen, B Jacques, S Dagorne - Organometallics, 2023 - ACS Publications
The present study details the synthesis and characterization of novel Zn (II)-based
organocations of the type [IPr*-Zn-R]+(IPr*= 1, 3-bis [2, 6-bis (diphenylmethyl)-4 …

The Facile Hydrolysis of Imidazolinium Chlorides (N‐Heterocyclic Carbene Precursors) Under Basic Aqueous Conditions

N Touj, JJ Ta**, N Tumanov… - … A European Journal, 2023 - Wiley Online Library
The hydrolysis of imidazolinium chlorides takes place readily in a basic water/
dichloromethane biphasic mixture at room temperature. Experimental parameters were …