Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds

S Rej, Y Ano, N Chatani - Chemical Reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

Recent Advances in Oxidative R1-H/R2-H Cross-Coupling with Hydrogen Evolution via Photo-/Electrochemistry: Focus Review

H Wang, X Gao, Z Lv, T Abdelilah, A Lei - Chemical reviews, 2019 - ACS Publications
Photo-/electrochemical catalyzed oxidative R1-H/R2-H cross-coupling with hydrogen
evolution has become an increasingly important issue for molecular synthesis. The dream of …

Construction of sulfur-containing moieties in the total synthesis of natural products

N Wang, P Saidhareddy, X Jiang - Natural Product Reports, 2020 - pubs.rsc.org
Covering: January 2013 to September 2018 Sulfur-containing natural products are a large
class of significant functional molecules. Many of these compounds exhibit potent biological …

Iridium-catalyzed asymmetric allylic substitution reactions

Q Cheng, HF Tu, C Zheng, JP Qu, G Helmchen… - Chemical …, 2018 - ACS Publications
In this review, we summarize the origin and advancements of iridium-catalyzed asymmetric
allylic substitution reactions during the past two decades. Since the first report in 1997, Ir …

Recent advances in radical C–H activation/radical cross-coupling

H Yi, G Zhang, H Wang, Z Huang, J Wang… - Chemical …, 2017 - ACS Publications
Research and industrial interest in radical C–H activation/radical cross-coupling chemistry
has continuously grown over the past few decades. These reactions offer fascinating and …

Decarboxylative reactions with and without light–a comparison

J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …

Radicals and Sulfur Dioxide: A Versatile Combination for the Construction of Sulfonyl‐Containing Molecules

K Hofman, NW Liu… - Chemistry–A European …, 2018 - Wiley Online Library
Molecules containing a sulfonyl functionality, such as sulfones, sulfonyl chlorides or
sulfonamides play an important role in organic chemistry and have found widespread …

Dual Ligand Enabled Nondirected C–H Chalcogenation of Arenes and Heteroarenes

SK Sinha, S Panja, J Grover, PS Hazra… - Journal of the …, 2022 - ACS Publications
Chalcogenide motifs are present as principal moieties in a vast array of natural products and
complex molecules. Till date, the construction of these chalcogen motifs has been restricted …

Decatungstate-Catalyzed C(sp3)–H Sulfinylation: Rapid Access to Diverse Organosulfur Functionality

PJ Sarver, NB Bissonnette… - Journal of the American …, 2021 - ACS Publications
Here we report the direct conversion of strong, aliphatic C (sp 3)–H bonds into the
corresponding alkyl sulfinic acids via decatungstate photocatalysis. This transformation has …