Chemical transformations that result in either the formation or cleavage of carbon–
heteroatom bonds are among the most important processes in the chemical sciences …

The biodegradation of compounds with C− F bonds is challenging due to the fact that these
bonds are stronger than the C− H bond in methane. In this work, results on the …

Toward the development of structural and functional models of the oxygen evolving complex
(OEC) of photosystem II, we report the synthesis of site-differentiated tetranuclear …

N-Heterocyclic Carbene-Catalyzed Construction of 1,3,5-Trisubstituted Benzenes from
Bromoenals and α-Cyano-β-methylenones | Organic Letters ACS ACS Publications C&EN …

Abstract High‐valent iron (IV)‐oxo intermediates are versatile oxidants in the
biotransformation of various substrates by metalloenzymes and catalyze essential reactions …

Binding of N2 and CO by the FeMo-cofactor of nitrogenase depends on the redox level of
the cluster, but the extent to which pure redox chemistry perturbs the affinity of high spin iron …

Tetranuclear Fe clusters have been synthesized bearing a terminal FeIII–oxo center
stabilized by hydrogen-bonding interactions from pendant (tert-butylamino) pyrazolate …

The synthesis and reactivity of a series of mononuclear nonheme iron complexes that carry
out intramolecular aromatic C–F hydroxylation reactions is reported. The key intermediate …

Atomically defined interfaces that maximize the density of active sites and harness the
electronic metal–support interaction are desirable to facilitate challenging multielectron …

Activation of inert C− H bonds such as those of methane are extremely challenging for
chemists but in nature, the soluble methane monooxygenase (sMMO) enzyme readily …