A quantum computing view on unitary coupled cluster theory

A Anand, P Schleich, S Alperin-Lea… - Chemical Society …, 2022 - pubs.rsc.org
We present a review of the Unitary Coupled Cluster (UCC) ansatz and related ansätze
which are used to variationally solve the electronic structure problem on quantum …

TeraChem: A graphical processing unit‐accelerated electronic structure package for large‐scale ab initio molecular dynamics

S Seritan, C Bannwarth, BS Fales… - Wiley …, 2021 - Wiley Online Library
TeraChem was born in 2008 with the goal of providing fast on‐the‐fly electronic structure
calculations to facilitate ab initio molecular dynamics studies of large biochemical systems …

Coupled-cluster techniques for computational chemistry: The CFOUR program package

DA Matthews, L Cheng, ME Harding… - The Journal of …, 2020 - pubs.aip.org
An up-to-date overview of the CFOUR program system is given. After providing a brief
outline of the evolution of the program since its inception in 1989, a comprehensive …

Even more efficient quantum computations of chemistry through tensor hypercontraction

J Lee, DW Berry, C Gidney, WJ Huggins, JR McClean… - PRX Quantum, 2021 - APS
We describe quantum circuits with only O~(N) Toffoli complexity that block encode the
spectra of quantum chemistry Hamiltonians in a basis of N arbitrary (eg, molecular) orbitals …

A Guided Tour of ab initio Nuclear Many-Body Theory

H Hergert - Frontiers in Physics, 2020 - frontiersin.org
Over the last decade, new developments in Similarity Renormalization Group techniques
and nuclear many-body methods have dramatically increased the capabilities of ab initio …

[HTML][HTML] An improved chain of spheres for exchange algorithm

B Helmich-Paris, B de Souza, F Neese… - The Journal of Chemical …, 2021 - pubs.aip.org
In the present work, we describe a more accurate and efficient variant of the chain-of-
spheres algorithm (COSX) for exchange matrix computations. Higher accuracy for the …

Reliably assessing the electronic structure of cytochrome P450 on today's classical computers and tomorrow's quantum computers

JJ Goings, A White, J Lee… - Proceedings of the …, 2022 - National Acad Sciences
An accurate assessment of how quantum computers can be used for chemical simulation,
especially their potential computational advantages, provides important context on how to …

[HTML][HTML] QMCPACK: Advances in the development, efficiency, and application of auxiliary field and real-space variational and diffusion quantum Monte Carlo

PRC Kent, A Annaberdiyev, A Benali… - The Journal of …, 2020 - pubs.aip.org
We review recent advances in the capabilities of the open source ab initio Quantum Monte
Carlo (QMC) package QMCPACK and the workflow tool Nexus used for greater efficiency …

Fault-tolerant quantum simulation of materials using Bloch orbitals

NC Rubin, DW Berry, FD Malone, AF White, T Khattar… - PRX Quantum, 2023 - APS
The simulation of chemistry is among the most promising applications of quantum
computing. However, most prior work exploring algorithms for block encoding, time evolving …

[HTML][HTML] TeraChem: Accelerating electronic structure and ab initio molecular dynamics with graphical processing units

S Seritan, C Bannwarth, BS Fales… - The Journal of …, 2020 - pubs.aip.org
Developed over the past decade, TeraChem is an electronic structure and ab initio
molecular dynamics software package designed from the ground up to leverage graphics …