Applications of Transition Metal-Catalyzed ortho-Fluorine-Directed C–H Functionalization of (Poly)fluoroarenes in Organic Synthesis
The synthesis of organic compounds efficiently via fewer steps but in higher yields is
desirable as this reduces energy and reagent use, waste production, and thus …
desirable as this reduces energy and reagent use, waste production, and thus …
Mechanochemical protocol facilitates the generation of arylmanganese nucleophiles from unactivated manganese metal
R Takahashi, P Gao, K Kubota, H Ito - Chemical science, 2023 - pubs.rsc.org
The direct synthesis of organomanganese reagents from organic halides and manganese
metal remains a challenge. Current solution-based approaches require the preparation of …
metal remains a challenge. Current solution-based approaches require the preparation of …
Visible-light-induced selective defluoroalkylations of polyfluoroarenes with alcohols
W Xu, Q Shao, C **a, Q Zhang, Y Xu, Y Liu, M Wu - Chemical Science, 2023 - pubs.rsc.org
To provide α-polyfluoroarylalcohols, a novel protocol for the selective defluoroalkylation of
polyfluoroarenes with easily accessible alcohols was reported via the cooperation of …
polyfluoroarenes with easily accessible alcohols was reported via the cooperation of …
9-Phenanthrenylvinyl-4′-pyridine and Its N-Methylated Analogue: From the Crystal Structure and Photoisomerization to Photophysical and Electrochemical …
Designing novel functional compounds is a key step in coordination and organic materials
chemistry. Herein, 9-phenanthrenylvinyl-4′-pyridine (9-PheVP), as a new ligand, has been …
chemistry. Herein, 9-phenanthrenylvinyl-4′-pyridine (9-PheVP), as a new ligand, has been …
Two polymorphs of fluoren-9-ylidene malononitrile
Abstract Fluoren-9-ylidene malononitrile (FM), a compound with two different crystal
structures, has been explored to better understand its polymorphism. Two polymorphs were …
structures, has been explored to better understand its polymorphism. Two polymorphs were …
Synthesis and Catalysis of NHC Coordinated Cyclometalated Palladium (II) Complexes with Bridging Hydroxide Ligands
I Nakajima, M Shimizu, Y Okuda… - Advanced Synthesis …, 2022 - Wiley Online Library
Addition reactions using organoboron compounds are one of the useful syntheses of various
functionalized alcohols, but they generally require a large quantity of bases. In this study, we …
functionalized alcohols, but they generally require a large quantity of bases. In this study, we …
Enantioselective Cu-Catalyzed Nucleophilic Substitutions of Polyfluoroarenes: Synthesis of Chiral Polyfluoroaryl Diarylmethanes
H Lin, X Huang, W Jiao, D Fang, M Wang, J Liao - Organic Letters, 2023 - ACS Publications
Optically pure diarylmethanes are frequently presented in pharmaceuticals and bioactive
molecules. However, minor efforts have been devoted to chiral polyfluoroarene-containing …
molecules. However, minor efforts have been devoted to chiral polyfluoroarene-containing …
3-Pyridylvinyl benzoxazole-derived multifunctional organic materials—from solid-state photoreactivity to photophysical and electrochemical properties
Development of multifunctional organic materials is an area of intense research interest in
organic materials chemistry. This study reports the synthesis, crystal structure elucidation …
organic materials chemistry. This study reports the synthesis, crystal structure elucidation …
Ligand‐Free Nickel‐Catalyzed Carbonyl Addition with Organoborons
SS Wu, X Ye, ZC Wang, SL Shi - ChemCatChem, 2024 - Wiley Online Library
Carbonyl addition serves as a strategically straightforward and versatile approach for
synthesizing alcohols, which are often encountered within bioactive molecules. Herein, we …
synthesizing alcohols, which are often encountered within bioactive molecules. Herein, we …
Pd‐Catalyzed Oxidative C− H Arylation of (Poly) fluoroarenes with Aryl Pinacol Boronates and Experimental and Theoretical Studies of its Reaction Mechanism
We report the synergistic combination of Pd (OAc) 2 and Ag2O for the oxidative C− H
arylation of (poly) fluoroarenes with aryl pinacol boronates (Ar‐Bpin) in DMF as the solvent …
arylation of (poly) fluoroarenes with aryl pinacol boronates (Ar‐Bpin) in DMF as the solvent …