Applications of Transition Metal-Catalyzed ortho-Fluorine-Directed C–H Functionalization of (Poly)fluoroarenes in Organic Synthesis

YP Budiman, RN Perutz, PG Steel, U Radius… - Chemical …, 2024 - ACS Publications
The synthesis of organic compounds efficiently via fewer steps but in higher yields is
desirable as this reduces energy and reagent use, waste production, and thus …

Mechanochemical protocol facilitates the generation of arylmanganese nucleophiles from unactivated manganese metal

R Takahashi, P Gao, K Kubota, H Ito - Chemical science, 2023 - pubs.rsc.org
The direct synthesis of organomanganese reagents from organic halides and manganese
metal remains a challenge. Current solution-based approaches require the preparation of …

Visible-light-induced selective defluoroalkylations of polyfluoroarenes with alcohols

W Xu, Q Shao, C **a, Q Zhang, Y Xu, Y Liu, M Wu - Chemical Science, 2023 - pubs.rsc.org
To provide α-polyfluoroarylalcohols, a novel protocol for the selective defluoroalkylation of
polyfluoroarenes with easily accessible alcohols was reported via the cooperation of …

9-Phenanthrenylvinyl-4′-pyridine and Its N-Methylated Analogue: From the Crystal Structure and Photoisomerization to Photophysical and Electrochemical …

TS Kannan, R Yadav, M Rukmini Sarma… - Crystal Growth & …, 2024 - ACS Publications
Designing novel functional compounds is a key step in coordination and organic materials
chemistry. Herein, 9-phenanthrenylvinyl-4′-pyridine (9-PheVP), as a new ligand, has been …

Two polymorphs of fluoren-9-ylidene malononitrile

B Kubendiran, G Pramanik, GK Kole - Journal of Molecular Structure, 2023 - Elsevier
Abstract Fluoren-9-ylidene malononitrile (FM), a compound with two different crystal
structures, has been explored to better understand its polymorphism. Two polymorphs were …

Synthesis and Catalysis of NHC Coordinated Cyclometalated Palladium (II) Complexes with Bridging Hydroxide Ligands

I Nakajima, M Shimizu, Y Okuda… - Advanced Synthesis …, 2022 - Wiley Online Library
Addition reactions using organoboron compounds are one of the useful syntheses of various
functionalized alcohols, but they generally require a large quantity of bases. In this study, we …

Enantioselective Cu-Catalyzed Nucleophilic Substitutions of Polyfluoroarenes: Synthesis of Chiral Polyfluoroaryl Diarylmethanes

H Lin, X Huang, W Jiao, D Fang, M Wang, J Liao - Organic Letters, 2023 - ACS Publications
Optically pure diarylmethanes are frequently presented in pharmaceuticals and bioactive
molecules. However, minor efforts have been devoted to chiral polyfluoroarene-containing …

3-Pyridylvinyl benzoxazole-derived multifunctional organic materials—from solid-state photoreactivity to photophysical and electrochemical properties

S Baskar, GK Kole - New Journal of Chemistry, 2024 - pubs.rsc.org
Development of multifunctional organic materials is an area of intense research interest in
organic materials chemistry. This study reports the synthesis, crystal structure elucidation …

Ligand‐Free Nickel‐Catalyzed Carbonyl Addition with Organoborons

SS Wu, X Ye, ZC Wang, SL Shi - ChemCatChem, 2024 - Wiley Online Library
Carbonyl addition serves as a strategically straightforward and versatile approach for
synthesizing alcohols, which are often encountered within bioactive molecules. Herein, we …

Pd‐Catalyzed Oxidative C− H Arylation of (Poly) fluoroarenes with Aryl Pinacol Boronates and Experimental and Theoretical Studies of its Reaction Mechanism

YP Budiman, MH Putra, MR Ramadhan… - Chemistry–An Asian …, 2024 - Wiley Online Library
We report the synergistic combination of Pd (OAc) 2 and Ag2O for the oxidative C− H
arylation of (poly) fluoroarenes with aryl pinacol boronates (Ar‐Bpin) in DMF as the solvent …