Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Sulfoxonium ylides are important surrogates for diazo compounds, and their use in industry
as safer alternatives has been evaluated during recent years. Beyond the known classical …

Two new visible-light-mediated strategies are described starting from aryldiazoacetates. The
first approach describes their reaction with azides to afford the corresponding imines, and …

A method for the synthesis of allyl substituted γ-butenolides via carbonyl ylide
rearrangement of vinyl sulfoxonium ylide-derived carbenes has been developed. At rt, the …

As pioneered by Corey and Chaykovsky, sulfoxonium ylides have had widespread
application in organic synthesis for more than a half century. In most of the reactions …

Sulfoxonium ylides are important synthetic precursors in various organic transformations.
Their synthetic potential was well explored in the synthesis of various bioactive natural …

A ruthenium‐catalysed cross‐olefination of diazo compounds and sulfoxonium ylides is
presented. Our reaction design exploits the intrinsic difference in reactivity of diazo …

A novel visible-light-promoted coupling of diazoketones with sulfoxonium ylides, employing
a violet light-emitting diode, is described under both batch and continuous flow conditions …

Herein, we report carbene-mediated benzannulation of vinyl sulfoxonium ylides with
electron-deficient alkynes and alkenes to synthesize oxygenated arenes. This protocol …