Lanthanide complexes as chiral probes exploiting circularly polarized luminescence

R Carr, NH Evans, D Parker - Chemical Society Reviews, 2012 - pubs.rsc.org
Optical probes that provide information about local chirality have been developed based on
changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide …

Lanthanide luminescence for biomedical analyses and imaging

JCG Bünzli - Chemical reviews, 2010 - ACS Publications
Gaining greater understanding of the structural and functional properties of living systems is
a key challenge in biology and medicine. On a more practical side, the diagnosis and …

Basics of lanthanide photophysics

JCG Bünzli, SV Eliseeva - Lanthanide luminescence: Photophysical …, 2011 - Springer
The fascination for lanthanide optical spectroscopy dates back to the 1880s when renowned
scientists such as Sir William Crookes, LeCoq de Boisbaudran, Eugène Demarçay or, later …

Spectroscopic properties and design of highly luminescent lanthanide coordination complexes

GF De Sa, OL Malta, C de Mello Donegá… - Coordination Chemistry …, 2000 - Elsevier
In this paper recent advances in the development of efficient light conversion molecular
devices (LCMD) based on lanthanide complexes are reviewed, with emphasis on the work …

New sensitizer-modified calix [4] arenes enabling near-UV excitation of complexed luminescent lanthanide ions

FJ Steemers, W Verboom, DN Reinhoudt… - Journal of the …, 1995 - ACS Publications
The synthesis is described of a series of calix [4] arenes with three different sensitizer
chromophores (“antenna”) attachedto the lower rim via a short spacer. In the Eu3+ and Tb3+ …

Lanthanide‐containing light‐emitting organic–inorganic hybrids: a bet on the future

LD Carlos, RAS Ferreira, VZ Bermudez… - Advanced …, 2009 - Wiley Online Library
Interest in lanthanide‐containing organic–inorganic hybrids has grown considerably during
the last decade, with the concomitant fabrication of materials with tunable attributes offering …

Tutorial on the Role of Cyclopentadienyl Ligands in the Discovery of Molecular Complexes of the Rare-Earth and Actinide Metals in New Oxidation States 136

WJ Evans - Organometallics, 2016 - ACS Publications
A fundamental aspect of any element is the range of oxidation states accessible for useful
chemistry. This tutorial describes the recent expansion of the number of oxidation states …

Structural, spectroscopic, and theoretical comparison of traditional vs recently discovered Ln2+ ions in the [K (2.2. 2-cryptand)][(C5H4SiMe3) 3Ln] complexes: the …

ME Fieser, MR MacDonald, BT Krull… - Journal of the …, 2015 - ACS Publications
The Ln3+ and Ln2+ complexes, Cp′ 3Ln, 1,(Cp′= C5H4SiMe3) and [K (2.2. 2-
cryptand)][Cp′ 3Ln], 2, respectively, have been synthesized for the six lanthanides …

Progress in lanthanides as luminescent probes

I Hemmilä, V Laitala - Journal of Fluorescence, 2005 - Springer
Lanthanides have recently found applications in different fields of biomolecular and medical
research. Luminescent lanthanide chelates have created interest mainly due to their unique …

Luminescence and energy transfer of the europium (III) tungstate obtained via the Pechini method

CA Kodaira, HF Brito, OL Malta, OA Serra - Journal of Luminescence, 2003 - Elsevier
This work presents the preparation of the europium tungstate compound, Eu2 (WO4) 3,
through the use of a polymeric precursor according to the Pechini method. In the preparation …