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Advances for Triangular and Sandwich-Shaped All-Metal Aromatics
M Wang, Y Wang - Molecules, 2024 - mdpi.com
Much experimental work has been contributed to all-metal σ, π and δ-aromaticity among
transition metals, semimetallics and other metals in the past two decades. Before our …
transition metals, semimetallics and other metals in the past two decades. Before our …
Noble‐noble strong union: Gold at its best to make a bond with a noble gas atom
This Review presents the current status of the noble gas (Ng)‐noble metal chemistry, which
began in 1977 with the detection of AuNe+ through mass spectroscopy and then grew from …
began in 1977 with the detection of AuNe+ through mass spectroscopy and then grew from …
[HTML][HTML] How far can one push the noble gases towards bonding?: a personal account
Noble gases (Ngs) are the least reactive elements in the periodic table towards chemical
bond formation when compared with other elements because of their completely filled …
bond formation when compared with other elements because of their completely filled …
Cooperative effects between π-hole triel and π-hole chalcogen bonds
J Zhang, W Li, J Cheng, Z Liu, Q Li - RSC advances, 2018 - pubs.rsc.org
MP2/aug-cc-pVTZ calculations have been performed on π-hole triel-and chalcogen-bonded
complexes involving a heteroaromatic compound. These complexes are very stable with …
complexes involving a heteroaromatic compound. These complexes are very stable with …
Superstrong Chemical Bonding of Noble Gases with Oxidoboron (BO+) and Sulfidoboron (BS+)
Inspired by the overwhelming exploration of noble gas–boron (Ng–B) bond containing
chemical compounds, the stability of the Ng bound BY+ and AlY+ (Y= O and S) has been …
chemical compounds, the stability of the Ng bound BY+ and AlY+ (Y= O and S) has been …
A theoretical investigation on boron–ligand cooperation to activate molecular hydrogen by a frustrated Lewis pair and subsequent reduction of carbon dioxide
The role of boron–ligand cooperation in activating molecular hydrogen by a set of six
frustrated Lewis pair (FLP) systems is explored using density functional theory. The results …
frustrated Lewis pair (FLP) systems is explored using density functional theory. The results …
Strong carbon–noble gas covalent bond and fluxionality in hypercoordinate compounds
Thermodynamic, kinetic, and chemical bonding analysis at the coupled cluster level has
been carried out for a series of hypercoordinated carbon compounds with formula CH4Ng2+ …
been carried out for a series of hypercoordinated carbon compounds with formula CH4Ng2+ …
Spodium bonding with noble gas atoms
The nature of the bonding between a neutral group 12 member (Zn3, Cd3 and Hg3) ring and
a noble gas atom was explored using quantum chemical simulations. Natural bond orbital …
a noble gas atom was explored using quantum chemical simulations. Natural bond orbital …