The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …

Organocatalysis has become a very powerful tool for precision macromolecular chemistry,
as judged by the number of articles published in this field in the past decade. A variety of …

Ten years have passed since the conception of what was termed Lewis pair polymerization
(LPP) that employs Lewis acid and base in pairs to not only activate monomers but also …

In virtue of the rising demand for metal-free polymeric materials, organocatalytic
polymerization has emerged and blossomed unprecedentedly in the past 15 years into an …

This review focuses on introducing and explaining the rare earth metal-mediated group
transfer polymerization (REM-GTP) of polar monomers and is composed of three main …

Polymerization‐induced self‐assembly (PISA) enables the synthesis at large scale of a wide
variety of functional nanoparticles. However, a large number of works are related to …

We describe the progress in precision polymerizations of specific kinds of N-
alkylacrylamides and N, N-dialkylacrylamides to produce polymers showing …

The quest for polymers that would be at the same time bio‐based and degradable after
usage, in addition to offering chemical post‐modification options, remains a daunting …

Phosphanes play an important role in various applications, serving as a class of organic
bases with basicities spanning more than 30 orders of magnitude. Accessing …