[HTML][HTML] From chemical gardens to chemobrionics

LM Barge, SSS Cardoso, JHE Cartwright… - Chemical …, 2015 - ACS Publications
Chemical gardens are perhaps the best example in chemistry of a self-organizing
nonequilibrium process that creates complex structures. Many different chemical systems …

Self-organization in precipitation reactions far from the equilibrium

E Nakouzi, O Steinbock - Science Advances, 2016 - science.org
Far from the thermodynamic equilibrium, many precipitation reactions create complex
product structures with fascinating features caused by their unusual origins. Unlike the …

Tubular precipitation and redox gradients on a bubbling template

DA Stone, RE Goldstein - Proceedings of the National Academy of …, 2004 - pnas.org
Tubular structures created by precipitation abound in nature, from chimneys at hydrothermal
vents to soda straws in caves. Their formation is controlled by chemical gradients within …

Characterization of iron–phosphate–silicate chemical garden structures

LM Barge, IJ Doloboff, LM White, GD Stucky… - Langmuir, 2012 - ACS Publications
Chemical gardens form when ferrous chloride hydrate seed crystals are added or
concentrated solutions are injected into solutions of sodium silicate and potassium …

[PDF][PDF] Formation and evolution of chemical gradients and potential differences across self-assembling inorganic membranes

F Glaab, M Kellermeier, W Kunz, E Morallon… - Angew …, 2012 - academia.edu
Spontaneous physical compartmentalization of chemically distinct reaction chambers is a
fundamental principle in living systems since the formation of the first protocells.[1] However …

Stalactite growth as a free-boundary problem: a geometric law and its platonic ideal

MB Short, JC Baygents, JW Beck, DA Stone… - Physical Review Letters, 2005 - APS
The chemical mechanisms underlying the growth of cave formations such as stalactites are
well known, yet no theory has yet been proposed which successfully accounts for the …

Genericity of confined chemical garden patterns with regard to changes in the reactants

F Haudin, V Brasiliense, JHE Cartwright… - Physical Chemistry …, 2015 - pubs.rsc.org
The growth of chemical gardens is studied experimentally in a horizontal confined geometry
when a solution of metallic salt is injected into an alkaline solution at a fixed flow rate …

Self-organization of layered inorganic membranes in microfluidic devices

Q Wang, MR Bentley, O Steinbock - The Journal of Physical …, 2017 - ACS Publications
Inorganic precipitate membranes play an important role in chemobrionics and origin of life
research. They can involve a range of catalytic materials, affect crystal habits, and show …

Shape-preserving conversion of calcium carbonate tubes to self-propelled micromotors

Q Wang, O Steinbock - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
The self-assembly of inorganic structures beyond the euhedral shape repertoire is a
powerful approach to grow hierarchically ordered materials and mesoscopic devices. The …

Chemical-garden formation, morphology, and composition. I. Effect of the nature of the cations

JHE Cartwright, B Escribano, CI Sainz-Díaz - Langmuir, 2011 - ACS Publications
We have grown chemical gardens in different sodium silicate solutions from several metal-
ion salts calcium chloride, manganese chloride, cobalt chloride, and nickel sulfate with …