Porous organic cages

X Yang, Z Ullah, JF Stoddart, CT Yavuz - Chemical Reviews, 2023 - ACS Publications
Porous organic cages (POCs) are a relatively new class of low-density crystalline materials
that have emerged as a versatile platform for investigating molecular recognition, gas …

Emerging electrolytes with fluorinated solvents for rechargeable lithium-based batteries

Y Wang, Z Li, Y Hou, Z Hao, Q Zhang, Y Ni… - Chemical Society …, 2023 - pubs.rsc.org
Electrolytes that can ensure the movement of ions and regulate interfacial chemistries for
fast mass and charge transfer are essential in many types of electrochemical energy storage …

Purely covalent molecular cages and containers for guest encapsulation

G Montà-González, F Sancenón… - Chemical …, 2022 - ACS Publications
Cage compounds offer unique binding pockets similar to enzyme-binding sites, which can
be customized in terms of size, shape, and functional groups to point toward the cavity and …

Metal–organic frameworks (MOFs) beyond crystallinity: amorphous MOFs, MOF liquids and MOF glasses

J Fonseca, T Gong, L Jiao, HL Jiang - Journal of Materials Chemistry A, 2021 - pubs.rsc.org
The field of metal–organic frameworks (MOFs) has been incorrectly believed to be purely
crystalline. However, non-crystalline MOFs (amorphous MOFs, MOF liquids, and MOF …

Industrial applications of ionic liquids

AJ Greer, J Jacquemin, C Hardacre - Molecules, 2020 - mdpi.com
Since their conception, ionic liquids (ILs) have been investigated for an extensive range of
applications including in solvent chemistry, catalysis, and electrochemistry. This is due to …

Advances in conjugated microporous polymers

JSM Lee, AI Cooper - Chemical reviews, 2020 - ACS Publications
Conjugated microporous polymers (CMPs) are a unique class of materials that combine
extended π-conjugation with a permanently microporous skeleton. Since their discovery in …

Metal–organic cages for molecular separations

D Zhang, TK Ronson, YQ Zou, JR Nitschke - Nature Reviews Chemistry, 2021 - nature.com
Separation technology is central to industries as diverse as petroleum, pharmaceuticals,
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …

A smart and responsive crystalline porous organic cage membrane with switchable pore apertures for graded molecular sieving

A He, Z Jiang, Y Wu, H Hussain, J Rawle, ME Briggs… - Nature Materials, 2022 - nature.com
Membranes with high selectivity offer an attractive route to molecular separations, where
technologies such as distillation and chromatography are energy intensive. However, it …

Postsynthetic modification: an enabling technology for the advancement of metal–organic frameworks

M Kalaj, SM Cohen - ACS Central Science, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of porous materials with immense chemical
tunability derived from their organic and inorganic building blocks. Presynthetic approaches …

The changing state of porous materials

TD Bennett, FX Coudert, SL James, AI Cooper - Nature Materials, 2021 - nature.com
Porous materials contain regions of empty space into which guest molecules can be
selectively adsorbed and sometimes chemically transformed. This has made them useful in …