[RhCp*Cl2]2-Catalyzed Indole Functionalization: Synthesis of Bioinspired Indole-Fused Polycycles

AN Singh Chauhan, G Mali, G Dua, P Samant… - ACS …, 2023 - ACS Publications
Polycyclic fused indoles are ubiquitous in natural products and pharmaceuticals due to their
immense structural diversity and biological inference, making them suitable for charting …

Rh (III)‐Catalyzed [4+ 2]‐Annulation of Indoles: Access to Functionalized Pyrimidoindolones Containing α‐Amino Acid Framework

DV Vorobyeva, AS Bubnova… - Asian Journal of …, 2023 - Wiley Online Library
An efficient method for the selective preparation of new CF3‐substituted α‐amino acid
derivatives decorated with pharmacophore pyrimido [1, 6‐a] indolone core has been …

Rhodium (III)‐Catalyzed [4+ 1] Oxidative Annulation of Amides with 1, 3‐enynes Through 1, 4‐Rhodium Migration

C Raji Reddy, M Subbarao, A Rathaur… - … Synthesis & Catalysis, 2023 - Wiley Online Library
Rh (III)‐catalyzed cascade oxidative C− H functionalization/aza‐annulation of indole and
pyrrole‐N‐carboxamides with 1, 3‐enynes involving 1, 4‐rhodium migration is disclosed …

Rh(III)-Catalyzed Oxidative Domino C–H/N–H Annulation: Diarylureas as Arylamine Donors for the Assembly of Indolo[2,1-a]isoquinolines

X Cao, Z Zhang, J Li, B Shi, M Li… - The Journal of Organic …, 2022 - ACS Publications
An efficient and convenient Rh (III)-catalyzed double aryl C (sp2)–H bond and N–H
activation and annulation reaction is reported for the synthesis of indolo [2, 1-a] …

Domino alkyne insertion/aldol reaction/aromatization of 2-alkynyl indole-3-carbaldehyde with 1, 3-diketones: entry to 2-indolyl phenols

CR Reddy, K Nair, AD Patil, RR Donthiri… - Organic & Biomolecular …, 2023 - pubs.rsc.org
A novel one-pot base-promoted insertion of indolyl 2-alkynes into a C–C single bond of 1, 3-
diketones, followed by intramolecular aldol reaction and dehydrative aromatization is …