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Water at charged interfaces
The ubiquity of aqueous solutions in contact with charged surfaces and the realization that
the molecular-level details of water–surface interactions often determine interfacial functions …
the molecular-level details of water–surface interactions often determine interfacial functions …
Multiscale modeling of aqueous electric double layers
From the stability of colloidal suspensions to the charging of electrodes, electric double
layers play a pivotal role in aqueous systems. The interactions between interfaces, water …
layers play a pivotal role in aqueous systems. The interactions between interfaces, water …
Construction of angstrom-scale ion channels with versatile pore configurations and sizes by metal-organic frameworks
Controllable fabrication of angstrom-size channels has been long desired to mimic
biological ion channels for the fundamental study of ion transport. Here we report a strategy …
biological ion channels for the fundamental study of ion transport. Here we report a strategy …
Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels
Biological fluoride ion channels are sub-1-nanometer protein pores with ultrahigh F−
conductivity and selectivity over other halogen ions. Develo** synthetic F− channels with …
conductivity and selectivity over other halogen ions. Develo** synthetic F− channels with …
A review of laser-induced crystallization from solution
Crystallization abounds in nature and industrial practice. A plethora of indispensable
products ranging from agrochemicals and pharmaceuticals to battery materials are …
products ranging from agrochemicals and pharmaceuticals to battery materials are …
Molecular origins of the zeta potential
M Předota, ML Machesky, DJ Wesolowski - Langmuir, 2016 - ACS Publications
The zeta potential (ZP) is an oft-reported measure of the macroscopic charge state of solid
surfaces and colloidal particles in contact with solvents. However, the origin of this readily …
surfaces and colloidal particles in contact with solvents. However, the origin of this readily …
Unraveling the molecular interface and boundary problems in an electrical double layer and electroosmotic flow
In a nanofluidic system, the electroosmotic flow (EOF) is a complex fluid transport
mechanism, where the formation of an electrical double layer (EDL) occurs ubiquitously at …
mechanism, where the formation of an electrical double layer (EDL) occurs ubiquitously at …
Ions Adsorbed at Amorphous Solid/Solution Interfaces Form Wigner Crystal-like Structures
When a surface is immersed in a solution, it usually acquires a charge, which attracts
counterions and repels co-ions to form an electrical double layer. The ions directly adsorbed …
counterions and repels co-ions to form an electrical double layer. The ions directly adsorbed …
Revealing molecular insights into surface charge and local viscosity in electroosmotic flows
The limitations of the continuum theory in predicting osmotic response at the nanoscale stem
from its lack of molecular-level insight into local fluid properties and the interfacial structure …
from its lack of molecular-level insight into local fluid properties and the interfacial structure …
Applied electric field effects on diffusivity and electrical double‐layer thickness
This study utilizes molecular dynamics (MD) simulations and continuum frameworks to
explore electroosmotic flow (EOF) in nanoconfined aqueous electrolytes, offering a …
explore electroosmotic flow (EOF) in nanoconfined aqueous electrolytes, offering a …