Water at charged interfaces

G Gonella, EHG Backus, Y Nagata… - Nature Reviews …, 2021 - nature.com
The ubiquity of aqueous solutions in contact with charged surfaces and the realization that
the molecular-level details of water–surface interactions often determine interfacial functions …

Multiscale modeling of aqueous electric double layers

M Becker, P Loche, M Rezaei, A Wolde-Kidan… - Chemical …, 2023 - ACS Publications
From the stability of colloidal suspensions to the charging of electrodes, electric double
layers play a pivotal role in aqueous systems. The interactions between interfaces, water …

Construction of angstrom-scale ion channels with versatile pore configurations and sizes by metal-organic frameworks

X Li, G Jiang, M Jian, C Zhao, J Hou… - Nature …, 2023 - nature.com
Controllable fabrication of angstrom-size channels has been long desired to mimic
biological ion channels for the fundamental study of ion transport. Here we report a strategy …

Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels

X Li, H Zhang, P Wang, J Hou, J Lu, CD Easton… - Nature …, 2019 - nature.com
Biological fluoride ion channels are sub-1-nanometer protein pores with ultrahigh F−
conductivity and selectivity over other halogen ions. Develo** synthetic F− channels with …

A review of laser-induced crystallization from solution

V Korede, N Nagalingam, FM Penha… - Crystal Growth & …, 2023 - ACS Publications
Crystallization abounds in nature and industrial practice. A plethora of indispensable
products ranging from agrochemicals and pharmaceuticals to battery materials are …

Molecular origins of the zeta potential

M Předota, ML Machesky, DJ Wesolowski - Langmuir, 2016 - ACS Publications
The zeta potential (ZP) is an oft-reported measure of the macroscopic charge state of solid
surfaces and colloidal particles in contact with solvents. However, the origin of this readily …

Unraveling the molecular interface and boundary problems in an electrical double layer and electroosmotic flow

M Masuduzzaman, BH Kim - Langmuir, 2022 - ACS Publications
In a nanofluidic system, the electroosmotic flow (EOF) is a complex fluid transport
mechanism, where the formation of an electrical double layer (EDL) occurs ubiquitously at …

Ions Adsorbed at Amorphous Solid/Solution Interfaces Form Wigner Crystal-like Structures

J Wang, H Li, M Tavakol, A Serva, B Nener, G Parish… - ACS …, 2023 - ACS Publications
When a surface is immersed in a solution, it usually acquires a charge, which attracts
counterions and repels co-ions to form an electrical double layer. The ions directly adsorbed …

Revealing molecular insights into surface charge and local viscosity in electroosmotic flows

M Masuduzzaman, BH Kim - Physics of Fluids, 2024 - pubs.aip.org
The limitations of the continuum theory in predicting osmotic response at the nanoscale stem
from its lack of molecular-level insight into local fluid properties and the interfacial structure …

Applied electric field effects on diffusivity and electrical double‐layer thickness

M Masuduzzaman, C Bakli, M Barisik, BH Kim - Small, 2024 - Wiley Online Library
This study utilizes molecular dynamics (MD) simulations and continuum frameworks to
explore electroosmotic flow (EOF) in nanoconfined aqueous electrolytes, offering a …