Understanding the unceasing evolution of Co (II) based single-ion magnets

PK Sahu, R Kharel, S Shome, S Goswami… - Coordination Chemistry …, 2023 - Elsevier
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …

3d single-ion magnets

GA Craig, M Murrie - Chemical Society Reviews, 2015 - pubs.rsc.org
One of the determining factors in whether single-molecule magnets (SMMs) may be used as
the smallest component of data storage, is the size of the barrier to reversal of the …

The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

JM Frost, KLM Harriman, M Murugesu - Chemical science, 2016 - pubs.rsc.org
Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …

Single ion magnets from 3d to 5f: developments and strategies

M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

AK Bar, C Pichon, JP Sutter - Coordination Chemistry Reviews, 2016 - Elsevier
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Large magnetic anisotropy in mononuclear metal complexes

S Gómez-Coca, D Aravena, R Morales… - Coordination Chemistry …, 2015 - Elsevier
This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …

First principles approach to the electronic structure, magnetic anisotropy and spin relaxation in mononuclear 3d-transition metal single molecule magnets

M Atanasov, D Aravena, E Suturina, E Bill… - Coordination Chemistry …, 2015 - Elsevier
In this review, a self-contained (although brief) introduction to electronic structure
calculations for single molecule magnet (SMM) properties is provided in conjunction with …

Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co (II) single-ion magnets

B Zhang, Y Zhou, HY Huang, XL Zhang… - Inorganic Chemistry …, 2024 - pubs.rsc.org
The mononuclear cobalt (II) complexes [Co (LN8)](BPh4) 2· C4H10O (1-BPh4) and [Co
(LN8)](NO3) 2· CH3CN (2-NO3)(LN8= 1, 4, 7, 10-tetrakis (2-pyridinemethyl)-1, 4, 7, 10 …

Slow magnetic relaxation in a mononuclear eight-coordinate Cobalt (II) complex

L Chen, J Wang, JM Wei, W Wernsdorfer… - Journal of the …, 2014 - ACS Publications
The quest for the single-molecular magnets (SMMs) based on mononuclear transition-metal
complexes is focused on the low-coordinate species. No transition-metal complex with a …