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Methane transformation by photocatalysis
Methane hydrate and shale gas are predicted to have substantial reserves, far beyond the
sum of other fossil fuels. Using methane instead of crude oil as a building block is, thus, a …
sum of other fossil fuels. Using methane instead of crude oil as a building block is, thus, a …
Photocatalytic conversion of methane: recent advancements and prospects
Abundant and affordable methane is not only a high‐quality fossil fuel, it is also a raw
material for the synthesis of value‐added chemicals. Solar‐energy‐driven conversion of …
material for the synthesis of value‐added chemicals. Solar‐energy‐driven conversion of …
Enabling specific photocatalytic methane oxidation by controlling free radical type
Selective CH4 oxidation to CH3OH or HCHO with O2 in H2O under mild conditions provides
a desired sustainable pathway for synthesis of commodity chemicals. However …
a desired sustainable pathway for synthesis of commodity chemicals. However …
A selective Au-ZnO/TiO2 hybrid photocatalyst for oxidative coupling of methane to ethane with dioxygen
Direct oxidation of methane to valuable chemicals is a great challenge as catalysts with both
high activity and selectivity for the activation of inert C–H bonds are required. Here, we …
high activity and selectivity for the activation of inert C–H bonds are required. Here, we …
Oxo dicopper anchored on carbon nitride for selective oxidation of methane
Selective conversion of methane (CH4) into value-added chemicals represents a grand
challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric …
challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric …
Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site
Natural gas, consisting mainly of methane (CH4), has a relatively low energy density at
ambient conditions (~ 36 kJ l− 1). Partial oxidation of CH4 to methanol (CH3OH) lifts the …
ambient conditions (~ 36 kJ l− 1). Partial oxidation of CH4 to methanol (CH3OH) lifts the …
Efficient and selective photocatalytic CH4 conversion to CH3OH with O2 by controlling overoxidation on TiO2
The conversion of photocatalytic methane into methanol in high yield with selectivity remains
a huge challenge due to unavoidable overoxidation. Here, the photocatalytic oxidation of …
a huge challenge due to unavoidable overoxidation. Here, the photocatalytic oxidation of …
Binary Au–Cu reaction sites decorated ZnO for selective methane oxidation to C1 oxygenates with nearly 100% selectivity at room temperature
L Luo, Z Gong, Y Xu, J Ma, H Liu, J **ng… - Journal of the American …, 2021 - ACS Publications
Direct and efficient oxidation of methane to methanol and the related liquid oxygenates
provides a promising pathway for sustainable chemical industry, while still remaining an …
provides a promising pathway for sustainable chemical industry, while still remaining an …
Selective photocatalytic oxidative coupling of methane via regulating methyl intermediates over metal/ZnO nanoparticles
Methane conversion to higher hydrocarbons requires harsh reaction conditions due to high
energy barriers associated with C− H bond activation. Herein, we report a systematic …
energy barriers associated with C− H bond activation. Herein, we report a systematic …
Nearly 100% selective and visible-light-driven methane conversion to formaldehyde via. single-atom Cu and Wδ+
Direct solar-driven methane (CH4) reforming is highly desirable but challenging, particularly
to achieve a value-added product with high selectivity. Here, we identify a synergistic …
to achieve a value-added product with high selectivity. Here, we identify a synergistic …