A review of oligo (arylene ethynylene) derivatives in molecular junctions
Oligo (arylene ethynylene)(OAE) derivatives are the “workhorse” molecules of molecular
electronics. Their ease of synthesis and flexibility of functionalisation mean that a diverse …
electronics. Their ease of synthesis and flexibility of functionalisation mean that a diverse …
[n]Cyclodibenzopentalenes as Antiaromatic Curved Nanocarbons with High Strain and Strong Fullerene Binding
Conjugated nanohoops provide a platform to study structure–property relationships; they are
attractive hosts for supramolecular chemistry as well as promising candidates as new …
attractive hosts for supramolecular chemistry as well as promising candidates as new …
Conjugated Nanohoop Polymers based on Antiaromatic Dibenzopentalenes for Charge Storage in Organic Batteries
With their bent π‐systems, cyclic conjugation and inherent cavities, conjugated nanohoops
are attractive for organic electronics applications. For ease of processing and morphological …
are attractive for organic electronics applications. For ease of processing and morphological …
Engineering the HOMO–LUMO gap of indeno [1, 2-b] fluorene
R Casares, Á Martínez-Pinel… - Journal of Materials …, 2022 - pubs.rsc.org
A direct, efficient and versatile strategy for the modulation of optoelectronic and magnetic
properties of indeno [1, 2-b] fluorene has been developed. 4-Substituted-2, 6 …
properties of indeno [1, 2-b] fluorene has been developed. 4-Substituted-2, 6 …
Antiaromatic sapphyrin isomer: transformation into contracted porphyrinoids with variable aromaticity
Sapphyrin is a pentapyrrolic expanded porphyrin with a 22π aromatic character. Herein, we
report the synthesis of a 20π antiaromatic sapphyrin isomer 1 by oxidative cyclization of a …
report the synthesis of a 20π antiaromatic sapphyrin isomer 1 by oxidative cyclization of a …
Synthesis and Characterization of Dibenzothieno[a,f]pentalenes Enabling Large Antiaromaticity and Moderate Open-Shell Character through a Small Energy Barrier …
Y Mizuno, A Nogata, M Suzuki… - Journal of the …, 2023 - ACS Publications
Experimental and theoretical rationalization of bond-shift valence tautomerization,
characterized by double-well potential surfaces, is one of the most challenging topics of …
characterized by double-well potential surfaces, is one of the most challenging topics of …
Enhancing the Antiaromaticity of s-Indacene through Naphthothiophene Fusion
Addressing the instability of antiaromatic compounds often involves protection with bulky
groups and/or fusion of aromatic rings, thus decreasing paratropicity. We report four …
groups and/or fusion of aromatic rings, thus decreasing paratropicity. We report four …
Chiral Dibenzopentalene‐Based Conjugated Nanohoops through Stereoselective Synthesis
Conjugated nanohoops allow to investigate the effect of radial conjugation and bending on
the involved π‐systems. They can possess unexpected optoelectronic properties and their …
the involved π‐systems. They can possess unexpected optoelectronic properties and their …
Enantiopure nanohoops through racemic resolution of diketo [n] CPPs by chiral derivatization as precursors to DBP [n] CPPs
Strained conjugated nanohoops are attractive synthetic targets due to the bending of their π-
system, which leads to intriguing optoelectronic properties, among others. By incorporating …
system, which leads to intriguing optoelectronic properties, among others. By incorporating …
Photoswitching of Local (Anti) Aromaticity in Biphenylene-Based Diarylethene Molecular Switches
Photoinduced tuning of (anti) aromaticity and associated molecular properties is currently in
the focus of attention for both tailoring photochemical reactivity and designing new materials …
the focus of attention for both tailoring photochemical reactivity and designing new materials …