The design and development of diverse functional systems in recent years have achieved a
plethora of landmarks in the two cornerstones of supramolecular chemistry, ie, molecular …

Conspectus Proteins exhibit high-binding affinity and selectivity, as well as remarkable
catalytic performance. Their binding pockets are hydrophobic but also contain polar and …

A rare gyrobifastigium architecture (GB) was constructed by self‐assembly of a tetradentate
donor (L) with PdII acceptor in DMSO. The GB was converted to its isomeric tetragonal barrel …

Molecular recognition in water involves contributions due to polar functional group
interactions, partial desolvation of polar and non-polar surfaces and changes in …

Molecule-inclusive closed cage compounds present a unique platform for molecular motion
in an isolated environment. This study showcases the incorporation of a tadpole-like polar …

We herein reported a design strategy for the construction of resorcin [4] arene-based metal–
organic complexes through adjusting auxiliary linkers. By precisely tuning 1, 4 …

The integrative implementation of multiple different components into metallosupramolecular
self‐assemblies requires sophisticated strategies to avoid the formation of statistical …

The synthesis, characterization, and chiroptical properties of a new class of
hemicryptophanes combining a phosphine moiety and a cyclotriveratrylene unit are …

Abstract Two-wall calix [4] pyrroles bearing two aryl substituents at diametrically opposed
meso-positions have been well explored toward the recognition and sensing of anionic …

A terpyridine-based supramolecular cage was successfully synthesized by the self-
assembly of a hexapodal metal–organic ligand with Zn2+. This metallo-cage exhibited two …