The flexibility of biomolecules enables them to adapt and transform as a result of signals
received from the external environment, expressing different functions in different contexts …

Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …

The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …

Post‐synthetic modification (PSM) is an effective approach for the tailored functionalization
of metal‐organic architectures, but its generalizability remains challenging. Herein we report …

Imaging of hypoxia in vivo helps with accurate cancer diagnosis and evaluation of
therapeutic outcomes. A PtII metallacage with oxygen‐responsive red phosphorescence …

Stimuli-responsive structural transformations between discrete coordination supramolecular
architectures not only are essential to construct smart functional materials but also provide a …

The fields of metal‐organic cages (MOCs) and metal‐organic frameworks (MOFs) are both
highly topical and continue to develop at a rapid pace. Despite clear synergies between the …

Understanding the composition, structure and stability of larger synthetic molecules is crucial
for their design, yet currently the analytical tools commonly used do not always provide this …

The assembly of metal–organic cages is governed by metal ion coordination preferences
and the geometries of the typically rigid and planar precursor ligands. Pd n L2 n cages are …

The development of artificial molecular systems capable of allosteric regulation has the
potential to unlock new functions related to the purification, sensing, and transformation of …