Carbon–carbon bond cleavage for late-stage functionalization

YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …

A polymer tethering strategy to achieve high metal loading on catalysts for Fenton reactions

L Wang, L Rao, M Ran, Q Shentu, Z Wu… - Nature …, 2023 - nature.com
The development of heterogenous catalysts based on the synthesis of 2D carbon-supported
metal nanocatalysts with high metal loading and dispersion is important. However, such …

M–N–C materials as heterogeneous catalysts for organic transformations

K **, R Bhadoria, P Starkov, N Kongi - Coordination Chemistry Reviews, 2023 - Elsevier
Abstract M–N–C (metal-nitrogen-carbon) materials have gained recognition as versatile and
effective catalysts in heterogeneous catalysis and electrocatalytic reactions. This review …

Coexistence of Fe nanoclusters boosting Fe single atoms to generate singlet oxygen for efficient aerobic oxidation of primary amines to imines

Z Ma, S Liu, N Tang, T Song, K Motokura, Z Shen… - ACS …, 2022 - ACS Publications
Tuning the geometric and electronic structure of the single-metal-atom catalysts via
simultaneous presence of metal nanoparticles or nanoclusters (NCs) offers an alternative …

Visible-Light Photocatalytic Aerobic C═C Bond Cleavage of Alkenes to Carbonyls by CsPbBr3 Nanocrystals

Q Fan, H Zhang, D Liu, C Yan, H Zhu… - The Journal of Organic …, 2023 - ACS Publications
Herein, we reported a facile and readily accessible visible-light-driven photocatalytic
protocol to induce oxidative cleavage of C═ C bonds to corresponding carbonyls using …

Oxidative Cleavage of Alkenes by O2 with a Non-Heme Manganese Catalyst

Z Huang, R Guan, M Shanmugam… - Journal of the …, 2021 - ACS Publications
The oxidative cleavage of C═ C double bonds with molecular oxygen to produce carbonyl
compounds is an important transformation in chemical and pharmaceutical synthesis. In …

Electronic and steric modification of Ni nanoparticle surface via N-doped carbon layers enables highly selective semihydrogenation of alkynes

X Wang, T Song, G Fu, Y Yang - ACS Catalysis, 2023 - ACS Publications
The selective semihydrogenation of alkynes to alkenes is of great importance in the
chemical industry. However, it remains a big challenge to achieve high catalytic activity and …

Photochemical organocatalytic aerobic cleavage of C═ C bonds enabled by charge-transfer complex formation

YX Chen, JT He, MC Wu, ZL Liu, K Tang, PJ **a… - Organic …, 2022 - ACS Publications
A novel visible-light-driven organocatalytic protocol to access aerobic oxidative cleavage of
olefins, promoted by sodium benzene sulfinate, is described herein. An array of alkenes …

Metal-free nitrogen-doped mesoporous carbons for the mild and selective synthesis of pyrroles from nitroarenes via cascade reaction

X Yu, M Miao, S Huo, X Tang, L Ni, S Liu… - ACS Applied Materials …, 2024 - ACS Publications
The cascade synthesis of pyrroles from nitroarenes is an attractive alternative strategy.
However, metal catalysts and relatively high temperatures cover the existing reported …

The synthesis of primary amines through reductive amination employing an iron catalyst

C Bäumler, C Bauer, R Kempe - ChemSusChem, 2020 - Wiley Online Library
The reductive amination of ketones and aldehydes by ammonia is a highly attractive method
for the synthesis of primary amines. The use of catalysts, especially reusable catalysts …